dibromo-2κ(2)Br-μ-(2,2'-[1,3-propanediylbis(nitrilomethylidyne)]diphenolato)-1κ(4)N,N',O,O':2κ(2)O,O'-copper(II)mercury(II) | 253599-30-3

• 英文名称: dibromo-2κ(2)Br-μ-(2,2'-[1,3-propanediylbis(nitrilomethylidyne)]diphenolato)-1κ(4)N,N',O,O':2κ(2)O,O'-copper(II)mercury(II)
• 英文别名: ([μ-bis(salicylidene)-1,3-propanediaminato]copper(II))dibromomercury(II)
• CAS: 253599-30-3
• 化学式: C₁₇H₁₆Br₂CuHgN₂O₂
• 分子量: 704.27
• InChiKey: IRVMALCZYJEHTJ-DQIPMIPLSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  N,N'-二亚水杨基-1,3-二氨基丙烷 在 NH₃ 作用下， 以 1,4-二氧六环 、 甲醇 、 乙醇 、 水 为溶剂， 生成 dibromo-2κ(2)Br-μ-(2,2'-[1,3-propanediylbis(nitrilomethylidyne)]diphenolato)-1κ(4)N,N',O,O':2κ(2)O,O'-copper(II)mercury(II)
  参考文献：
  名称：

  {[μ-Bis(salicylidene)-1,3-propanediaminato]-copper(II)}dibromomercury(II)

  摘要：

  In the title complex, dibromo-2 kappa(2)Br-mu-{2,2'-[1,3-propanediylbis (nitrilomethylidyne)] diphenolato}-1 kappa(4)N,- N',O,O':2 kappa(2)O,O'-copper(II)mercury(II), [CU(C17H16- N2O2){HgBr2], the Cu-II and Hg-II atoms are doubly bridged by the two O atoms of the N,N'-bis(salicylidene)-1,3-propanediaminate (SALPD(2-)) ligand, and the two N atoms of this ligand complete the distorted square-planar coordination around the Cu-II atom. The coordination around the Hg-II atom is distorted tetrahedral, involving two bridging O atoms and two Br atoms. The bond angles in the HgCuO2 bridging plane are in the range 1.4 (1)-108.0(2)degrees. The Cu ... Hg distance is 3.523 (3) Angstrom.

  DOI：

  10.1107/s0108270199009191