[(C5H5)Ti(2,6-dimethylphenyl isocyanide)2I2] | 1029982-63-5

• 英文名称: [(C5H5)Ti(2,6-dimethylphenyl isocyanide)2I2]
• CAS: 1029982-63-5
• 化学式: C₂₃H₂₃I₂N₂Ti
• 分子量: 629.138
• InChiKey: VJYGOLJUQUCIMT-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [(C5H5)Ti(2,6-dimethylphenyl isocyanide)4I] 、 碘 以 甲苯 为溶剂， 生成 [(C5H5)Ti(2,6-dimethylphenyl isocyanide)2I2]
  参考文献：
  名称：

  Synthesis and characterization of titanium tetraisocyanide complexes, [CpTi(CNXyl)4E], E=I, SnPh3, and SnMe3

  摘要：

  Oxidation of [CpTi(CO)(4)](-) by I(2), Ph(3)SnCl, and Me(3)SnCl in the presence of four equivalents of CNXyl, Xyl = 2,6-dimethylphenyl, affords unprecedented titanium tetraisocyanide complexes, [CpTi(CNXyl)(4)E], E = I, SnPh(3), SnMe(3). These have been isolated and characterized by spectroscopic methods as well as single-crystal X-ray crystallography. A by-product of the iodine reaction was the Ti(III) complex, [CpTi(CNXyl)(2)I(2)], which was also characterized by X-ray crystallography. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.11.047