| 1424368-28-4

• CAS: 1424368-28-4
• 化学式: C₇₀H₉FeN
• 分子量: 919.695
• InChiKey: MLOXFBYVABUPLE-OGHHPKGASA-N

反应信息

• 作为产物：
  描述：

  1-azidoferrocene 、 足球烯 以 氯苯 为溶剂， 反应 24.0h， 以16%的产率得到
  参考文献：
  名称：

  Syntheses of N-bridged ferrocene/porphyrin-fullerene dyads and influence of iminofullerene isomers on the attached chromophores

  摘要：

  N-Ferrocene (Fc)/porphyrin (Por) [5,6]-open azafulleroids and [6,6]-closed aziridinofullerenes have been synthesized for the first time. Electrochemical measurements revealed that chromophores attached to [5,6]-open azafulleroids are more easily oxidizable than those attached to [6,6]-closed aziridinofullerenes. This was attributed to the delocalization degree of the nitrogen lone-electron pair involved in aziridinofullerene that is larger than that in azafulleroid. (c) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2013.01.061