Fc(CH₂)₆PH₂(BH₃) | 1599442-16-6

• 英文名称: Fc(CH₂)₆PH₂(BH₃)
• CAS: 1599442-16-6
• 化学式: C₁₆H₂₆BFeP
• 分子量: 316.014
• InChiKey: JRKCZOWRIIREAL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  dimethyl sulfide borane 、 Fc(CH2)6PH2 以 四氢呋喃 、 正己烷 为溶剂， 反应 0.25h， 以26%的产率得到Fc(CH₂)₆PH₂(BH₃)
  参考文献：
  名称：

  Extending the range of stabilised, primary and secondary phosphanes containing ferrocenyl or ruthenocenyl groups

  摘要：

  Alkylation reactions of FcCH(2)P(CH2OH)(2) [ Fc = (eta(5)-C5H5)Fe(eta(5)-C5H4)] with MeI or p-BrCH2C6H4NO2, or of CyP(CH2OH)(2) with [FcCH(2)NMe(3)(+)]I gave hydroxymethylphosphanes FcCH(2)PR(CH2OH) (R = Me, Cy or p-O-2-NCH2C6H4) which were converted to the new secondary phosphanes FcCH(2)PHR on treatment with Na-2-S2O5. A series of longer-chain ferrocenylalkyl primary phosphanes Fc(CH2)(n)PH2 was also prepared by reactions of the bromoalkylferrocenes Fc(CH2)(n)Br (n = 4, 6 or 11) with P(CH2OH)(3) to give intermediate hydroxymethylphosphanes Fc(CH2)(n)P(CH2OH)(2), followed by reaction with Na2S2O5. Fc(CH2)(6)PH2 was converted into its crystalline BH3 adduct, which was structurally characterised. The synthesis of the new ruthenocene (Rc)-derived primary phosphane RcCH(2)PH(2), the first example of a ruthenocene-derived primary phosphane, is also reported. (C) 2014 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2014.01.049