Phosphorane Iminato Complexes of Manganese and Cobalt with Heterocubane Structure
作者:Hans-Joachim Mai、Rolf Meyer zu Köcker、Sigrid Wocadlo、Werner Massa、Kurt Dehnicke
DOI:10.1002/anie.199512351
日期:1995.6.16
Mn4N4 and Co4N4 cubes with almost square faces are found in the title compounds 1 and 2. They were obtained by the melt reaction of the anhydrous dihalides MnI2 and CoCl2, and Me3SiNPEt3. Complexes 1 and 2 are the first phosphorane iminato complexes of manganese(II) and cobalt(II) with heterocubane structure.
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