(η3-1-methyl carbonate-allyl)palladium chloride dimer | 909547-26-8

• 英文名称: (η3-1-methyl carbonate-allyl)palladium chloride dimer
• CAS: 909547-26-8
• 化学式: C₁₀H₁₄Cl₂O₆Pd₂
• 分子量: 513.964
• InChiKey: GDSORGKTORZBKA-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  lithium tetrachloropalladate 、 以 四氢呋喃 为溶剂， 以57%的产率得到(η3-1-methyl carbonate-allyl)palladium chloride dimer
  参考文献：
  名称：

  Synthesis and structural features of α-acyloxy-(η3-allyl)palladium complexes

  摘要：

  alpha-Acetoxy (eta(3)-allyl)palladium complexes were prepared from acyloxy functionalized allylsilanes under mild conditions and in good isolated yields. The substituent and ligand effects of the acetoxy group on the palladium-allyl bonding were studied by X-ray diffraction. These studies show that the acetoxy group generates a strongly deformed bonding between the metal atom and the allyl moiety. This unsymmetrical bonding is modulated by the sigma-donor/pi-acceptor properties of the ligands. The C-13 NMR studies indicated that the shift values correlate with the carbon-palladium bond lengths and the inductive effects of the acetoxy group. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2006.05.013