| 153985-03-6

• CAS: 153985-03-6
• 化学式: CO*ClH
• 分子量: 64.4713
• InChiKey: XSQFKBKDSSEVBS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.02
• 重原子数：
  3.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  17.07
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为产物：
  描述：

  盐酸 、 一氧化碳 以 gaseous matrix 为溶剂， 生成
  参考文献：
  名称：

  The rotational spectra of weakly bound dimers of carbon monoxide and the hydrogen halides HX (X=F, Cl, and Br)

  摘要：

  A microwave spectrometer was used to measure the molecular constants of the dimers and to establish the linearity of the atom arrangement. (AIP)

  DOI：

  10.1063/1.439859

文献信息

• Matrix isolation study of the photochemically induced reaction of ozone with dibromochloromethane and bromodichloromethane in solid argon at 14 K. FT-IR spectra of the complexes C(O)HCl  · · ·  BrX, C(O)HBr  · · ·  XCl, C(O)BrCl  · · ·  HX, (OC)(HCl)(Br2), (OC)(HBr)(Cl2), and (OC)(BrCl)(HX) (where X = Br or Cl)
  作者：Robin J. H. Clark、Jonathan R. Dann、Loraine J. Foley

  DOI：10.1039/a805799k

  日期：——

  dihalogen abstraction reactions. Upon further irradiation the carbonyl complexes dissociate to form the new carbon monoxide complexes (OC)(HCl)(Br2), (OC)(HBr)(Cl2), and (OC)(BrCl)(HX). Thus the photo-induced reactions of ozone with trihalogenomethanes lead to the formation of new carbonyl and carbon monoxide complexes whose vibrational properties are well characterised by FT-IR spectroscopy. Suggested pathways

  FT-IR光谱表明，在14 K的氩气中，臭氧/二溴氯甲烷或臭氧/溴二氯甲烷的石英过滤光（λ > 240 nm）光解会导致羰基···路易斯酸络合物C（ O）HCl ·· BrX，C（O）HBr ·· XCl，C（O）BrCl ·· HX和C（O）Cl 2 ··· HBr，其中X = Br或Cl，取决于使用三卤代甲烷。这些配合物中的几种是新的，是通过卤化氢或二卤素提取反应形成的。在进一步辐射下，羰基配合物解离形成新的一氧化碳配合物（OC）（HCl）（Br 2），（OC）（HBr）（Cl 2））和（OC）（BrCl）（HX）。因此，臭氧与三卤代甲烷的光诱导反应导致形成新的羰基和一氧化碳配合物，这些化合物的振动特性已通过FT-IR光谱得到了很好的表征。提出了光解的建议途径。
• Infrared matrix isolation studies of the reactions of dichloro- and dibromomethane with atomic oxygen
  作者：C. Lugez、A. Schriver、L. Schriver-Mazzuoli、E. Lasson、C. J. Nielsen

  DOI：10.1021/j100147a010

  日期：1993.11

  The reactions of atomic oxygen with CH2Cl2 and CH2Br2 trapped in argon matrices have been studied by FTIR spectroscopy. O(1D) and (O(3P))-P-3 were generated in situ by UV photolysis of co-deposited ozone. Products were identified by employing O-18 and scrambled O-18/O-16 ozone as well as deuterated methylene halides. Kinetic studies performed on both CH2Cl2 and CH2Br2 With O(1D) under the same experimental conditions allowed the reaction pathways to be determined. With CH2Br2 as parent molecule, three routes were evident leading to (i) CHOBr, (ii) CO...(HBr)2, and (iii) CH2O. With CH2Cl2 as parent molecule, only the first two channels were observed. Carbonyl compounds rapidly decomposed under irradiation, and CO...(HX)2 was also produced as a secondary species.