[RuCl2(1,4-bis(diphenylphosphino)butane)(2-methyldiaminoethane)] | 1384871-84-4

• 英文名称: [RuCl2(1,4-bis(diphenylphosphino)butane)(2-methyldiaminoethane)]
• CAS: 1384871-84-4
• 化学式: C₃₁H₃₈Cl₂N₂P₂Ru
• 分子量: 672.58
• InChiKey: IMLFNPBWAGCICR-JHKJZGKLSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  tris(triphenylphosphine)ruthenium(II) chloride 、 1,2-丙二胺 、 1,4-双(二苯基膦)丁烷 以 二氯甲烷 为溶剂， 以95%的产率得到[RuCl2(1,4-bis(diphenylphosphino)butane)(2-methyldiaminoethane)]
  参考文献：
  名称：

  Synthesis, spectral, thermal, X-ray single crystal of new RuCl2(dppb)diamine complexes and their application in hydrogenation of Cinnamic aldehyde

  摘要：

  The preparation of new three trans-[RuCl2(dppb)(N-N)] with mixed diamine (N-N) and 1,4-bis-(diphenylphosphino)butane (dppb) ligands, starting from RuCl2(PPh3)(3) as precursor is presented. The complexes are characterized on the basis of elemental analysis. IR, H-1, C-13 and P-31(H-1)NMR, FAB-MS, TG/DTA and single crystal X-ray diffraction studies. Complex (2L(1)) crystallizes in the monoclinic unit cells with the space group P2(1). The catalysts are evaluated for their Cinnamic aldehyde hydrogenation. The catalysts show excellent activity and selectivity for the unsaturated carbonyl compound under mild conditions. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2012.03.089