cis-RuMeCN(CO)2(PMe3)2 | 116635-45-1

• 英文名称: cis-RuMeCN(CO)2(PMe3)2
• CAS: 116635-45-1
• 化学式: C₁₀H₂₁NO₂P₂Ru
• 分子量: 350.3
• InChiKey: KPOXQCYXULEXCI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  cis-RuMeCN(CO)2(PMe3)2 在 一氧化碳 作用下， 以 正己烷 、 二氯甲烷 为溶剂， 生成 cis-Ru(COMe)CN(CO)2(PMe3)2
  参考文献：
  名称：

  Cardaci; Reichenbach; Bellachioma, Organometallics, 1988, vol. 7, # 12, p. 2475 - 2479

  摘要：

  DOI：
• 作为产物：
  描述：

  以 not given 为溶剂， 生成 cis-RuMeCN(CO)2(PMe3)2
  参考文献：
  名称：

  Oxidative addition of methyl iodide to monosubstituted and disubstituted derivatives of ruthenium pentacarbonyl: preparation of neutral and ionic complexes of ruthenium

  摘要：

  The oxidative addition of CH3I to Ru(CO)4PMe3 (1) gives the methyl complex Ru(CO)3PMe3(CH3)I (3); with PMe3 complex 3 gives the acetyl complexes Ru(CO)2(PMe3)2(COCH3)I (isomers 10a and 10b), which, by decarbonylation, give Ru(CO)2(PMe3)2(CH3)I (4). Complex 4 can also be obtained by oxidative addition of CH3I to Ru(CO)3(PMe3)2 (2). Complex 4 reacts at room temperature with the nucleophiles CO, PMe3, and P(OMe)3 giving the acetyl complexes (structures 7, 15, and 18, respectively), which at higher temperatures isomerize to 8, 16, and 19, respectively. Decarbonylation of these complexes gives complex 4 (in the case of CO), complex 12 (in the case of PMe3), and complex 13 (in the case of P(OMe)3). This last complex reacts with different nucleophiles (PMe3, P(OMe)3) and gives the ionic tetraphosphine complexes [Ru(CO)(PMe3)3P(OMe)3(CH3)]I (22) and [Ru(CO)(PMe3)2(P(OMe)3)2(CH3)]BPh4 (24), respectively. The trisubstituted cyano derivative Ru(CO)(PMe3)2P-(OMe)3(CH3)CN (14) is obtained by the reaction of complex 22 with KCN in acetone. The structures of the various complexes were assigned, in most cases, on the basis of spectroscopic (IR, H-1, P-31, C-13) information.

  DOI：

  10.1021/ic00057a011