[(CH3COCHCOC6H5)2Al(μ-OCH(CH3)2)2Al(OCH2-2-C5H4N)2] | 504395-75-9

• 英文名称: [(CH3COCHCOC6H5)2Al(μ-OCH(CH3)2)2Al(OCH2-2-C5H4N)2]
• CAS: 504395-75-9
• 化学式: C₃₈H₄₄Al₂N₂O₈
• 分子量: 710.739
• InChiKey: JZTBOXVUMONABF-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  2-吡啶甲醇 、 [(CH3COCHCOC6H5)2Al(μ-OCH(CH3)2)2Al(OCH(CH3)2)2] 以 苯 为溶剂， 以99%的产率得到[(CH3COCHCOC6H5)2Al(μ-OCH(CH3)2)2Al(OCH2-2-C5H4N)2]
  参考文献：
  名称：

  SYNTHESIS AND CHARACTERIZATION OF SOME UNIQUE HETEROCYCLIC DERIVATIVES CONTAINING ALUMINIUM(III) ATOMS IN DIFFERENT CO-ORDINATION STATES. I. REACTIONS OFBIS(β-DIKETONATO)-ALUMINIUM(III)-DI-μ-ISOPROPOXO-DI-ISOPROPOXOALUMINIUM(III) WITH 2-PYRIDYLMETHANOL

  摘要：

  Reactions of bis(beta-diketonato)aluminium(Ill)-di-mu-isopro-poxo-di-isopropoxoaluminium(III), [(CH3COCHCOR)(2)Al-(mu-OPr-i)(2)Al(OPr-i)(2)] with 2-pyridylmethanol, (C5H4N-2CH(2)OH) in 1:1 and 1:2 molar ratios in refluxing anhydrous benzene resulted in the synthesis of [(CH3COCHCOR)(2)Al(mu-OPr-i)(2)Al(OCH2-2-C5H4N)(OPr-i)] [where R = CH3 (1), -OC2-H-5 (3), and -C6H5 (5)] and [(CH3COCHCOR)(2)Al(mu-OPr-i)(2)Al(OCH2-2-C5H4N)(2)] [where R = CH3 (2), -OC2H5 (4), and -C6H5 (6)], respectively. All of these compounds are sharp melting solids and are soluble in a variety of organic solvents (e.g., benzene, chloroform and dimethyl sulfoxide) except [(CH3COCHCOOC2H5)(2)Al(mu-OPr-i)(2)AI(OCH2-2-C5H4N)(2)], which is insoluble in benzene but soluble in chloroform and dimethylsulfoxide. All of these derivatives show a dinuclear structure in benzene. All of the above derivatives have been characterized by elemental analyses, molecular weight determinations, IR and NMR (H-1, C-13 and Al-27) and FAB mass spectral studies.

  DOI：

  10.1081/sim-120016470