| 422322-39-2

• CAS: 422322-39-2
• 化学式: CF₃O₃S*C₂₅H₃₁N₂Ru
• 分子量: 609.675
• InChiKey: JBUOFADDXUFDEQ-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  [(η(5)-pentamethylcyclopentadienyl)Ru(η(6)-C6H5CHO)]CF3SO3 、 N,N-二甲基-对苯二胺 以 二氯甲烷 为溶剂， 以70%的产率得到
  参考文献：
  名称：

  Cp*Ru+ complexes of benzylideneaniline and salicylideneaniline

  摘要：

  The reaction product of Cp*Ru(CH3CN)(3)(+) OSO2CF3- with salicylaldehyde yielded (1) which reacted with a series of aniline derivatives to produce air-stable solids. These products were characterized by H-1 and C-13 NMR spectrometry and UV-Vis spectroscopy. Solvatochromism studies of these products revealed that the p-NH2 and p-N(CH3)(2) derivatives exhibit relatively large values of molecular hyperpolarizability and have the potential to exhibit nonlinear optical properties. These derivatives were further studied by electrochemical investigations. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(01)00733-2