[2-((dimethylamino)methyl)phenyl]diazidobismuthane | 1262035-55-1

• 英文名称: [2-((dimethylamino)methyl)phenyl]diazidobismuthane
• CAS: 1262035-55-1
• 化学式: C₁₈H₂₄Bi₂N₁₄
• 分子量: 854.443
• InChiKey: KUNQUGLAYPMQRD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  迭氮银 、 [2-((dimethylamino)methyl)phenyl]diiodobismuthane 以 四氢呋喃 为溶剂， 以98%的产率得到[2-((dimethylamino)methyl)phenyl]diazidobismuthane
  参考文献：
  名称：

  Mono- and Diazides of Bismuth

  摘要：

  Bis[2-((dimethylamino)methyl)phenyl]azidobismuthane, [2-(Me2NCH2)C6H4](2)BiN3, and [2-((dimethylamino)methyl)phenyl]diazidobismuthane, [2-(Me2NCH2)C6H4]Bi(N-3)(2), were synthesized and fully characterized. [2-(Me2NCH2)C6H4](2)BiN3 and [2-(Me2NCH2)C6H4]Bi(N-3)(2) represent rare examples of bismuth azides. The structures of both azide compounds were determined by single-crystal X-ray diffraction. While for the monoazide [2-(Me2NCH2)C6H4](2)BiN3 a monomeric species was found, the diazide [2-(Me2NCH2)C6H4]Bi(N-3)(2) dimerizes in the solid state, exhibiting two bridging azido groups. Furthermore, weak van der Waals interactions between these centrosymmetric dimers lead to a chainlike structure in the crystal.

  DOI：

  10.1021/om1009796