| 136868-06-9

• CAS: 136868-06-9
• 化学式: C₁₅H₂₈N₂Rh*ClO₄
• 分子量: 438.757
• InChiKey: IVWLZAMLVPXQPL-PHFPKPIQSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  在 CO 、 triphenyl phosphine 作用下， 以 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  Rhodium(I) complexes with unsymmetric aliphatic diamines. Crystal structure of [Rh(C8H12)(C7N2H16)][RhCl2(C8H12)] and [Rh(C8H12)(C7N2H16)]ClO4

  摘要：

  Reactions of [Rh(COD)Cl]2 with unsymmetric aliphatic diamines (LL') have been studied. The 1:1 ligand:dimer reactions yield ionic products [Rh(C8H12)(LL')][RhCl2(C8H12)] that in solution are in equilibrium with the respective binuclear compounds {[RhCl2(C8H12)]2(mu-LL')}. The X-ray structure of [Rh(C8H12)(C7N2H16)][RhCl2(C8H12)] is presented. When the reactions are performed in media saturated with CO, carbonylated ion-pair complexes are obtained. The 2:1 ligand:dimer reactions afford neutral tetracoordinated [Rh(COD)(LL')Cl] compounds bonded through the primary amino group, and show rapid interchange of olefinic protons at room temperature. The synthesis and properties of cationic complexes of general formulae [Rh(COD)(LL')]ClO4 and [Rh(CO)(PPh3)(LL')]ClO4 are also discussed. Cyclooctadiene compounds show association processes in acetone solution, though they are monomeric in the solid state. The X-ray structure of [Rh(C8H12)(C7N2H16)]ClO4 indicates the existence of hydrogen bonding between the oxygens in the perchlorate anion and the primary amino group in the cation.

  DOI：

  10.1016/s0020-1693(00)85446-8
• 作为产物：
  描述：

  N-乙基-2-氨甲基吡咯烷 、 bis(cyclooctadiene)rhodium(I) perchlorate 以 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  Rhodium(I) complexes with unsymmetric aliphatic diamines. Crystal structure of [Rh(C8H12)(C7N2H16)][RhCl2(C8H12)] and [Rh(C8H12)(C7N2H16)]ClO4

  摘要：

  Reactions of [Rh(COD)Cl]2 with unsymmetric aliphatic diamines (LL') have been studied. The 1:1 ligand:dimer reactions yield ionic products [Rh(C8H12)(LL')][RhCl2(C8H12)] that in solution are in equilibrium with the respective binuclear compounds {[RhCl2(C8H12)]2(mu-LL')}. The X-ray structure of [Rh(C8H12)(C7N2H16)][RhCl2(C8H12)] is presented. When the reactions are performed in media saturated with CO, carbonylated ion-pair complexes are obtained. The 2:1 ligand:dimer reactions afford neutral tetracoordinated [Rh(COD)(LL')Cl] compounds bonded through the primary amino group, and show rapid interchange of olefinic protons at room temperature. The synthesis and properties of cationic complexes of general formulae [Rh(COD)(LL')]ClO4 and [Rh(CO)(PPh3)(LL')]ClO4 are also discussed. Cyclooctadiene compounds show association processes in acetone solution, though they are monomeric in the solid state. The X-ray structure of [Rh(C8H12)(C7N2H16)]ClO4 indicates the existence of hydrogen bonding between the oxygens in the perchlorate anion and the primary amino group in the cation.

  DOI：

  10.1016/s0020-1693(00)85446-8