pyridinum sulfonate chlorochromate | 849518-09-8

• 英文名称: pyridinum sulfonate chlorochromate
• CAS: 849518-09-8
• 化学式: C₅H₆NO₃S*ClCrO₃
• 分子量: 295.621
• InChiKey: ZITKMGNESWDOOO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  吡啶 、 chromium(VI) oxide 、 氯磺酸 以 氯仿 为溶剂， 生成 pyridinum sulfonate chlorochromate
  参考文献：
  名称：

  Efficient Selective Oxidation of Organic Substrates Using Pyridinum Sulfonate Halochromate Under Solvent-Free Conditions and Microwave Irradiation: Experimental and Theoretical Study

  摘要：

  A convenient and rapid method has been developed for the selective oxidation of several types of alcohols to related carbonyl compounds under solvent-free conditions. In this study, the authors report the microwave-assisted selective oxidation of alcohols and a number of organic compounds with pyridinum sulfonate chlorochromate (PSCC) and pyridinum sulfonate fluorochromate (PSFC). The density functional theory calculations were made at B3LYP/6-31G* levels of theory and thermodynamic data supported the proposed mechanism involving formation of a halochromate ester, which showed that PSFC should be a more capable oxidant than PSCC. The oxidation products are easily obtained in short reaction time with good yields.

  DOI：

  10.1080/15533174.2011.615045