| 1312591-41-5

• CAS: 1312591-41-5
• 化学式: C₃₂H₄₆N₁₀Ni₄O₁₂*H₂O
• 分子量: 1015.55
• InChiKey: OFVSUHAPKUJPHD-DXQAPUJXSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2,6-二甲酰-4-甲基苯酚 、 水 、 C.I.酸性橙108 、 nickel(II) acetate tetrahydrate 、 sodium azide 以 甲醇 为溶剂， 以32%的产率得到
  参考文献：
  名称：

  Three azido-, alk/phenoxido- and acetato-bridged tetranuclear nickel complexes featuring defective double-cubane

  摘要：

  Three new tetranuclear nickel(II) complexes of general formula [Ni-4(L)(2)(N-3)(2)(CH3COO)(2)(CH3O)(2)](2)center dot xCH(3)OH center dot yH(2)O (HL = HL1, HL2 and HL3; x = 0, y = 1 for 1; x = 2, y = 0 for 2 and x = 2, y = 4 for 3) were synthesized and characterized by single crystal X-ray diffraction and magnetic measurements. Single crystal X-ray studies reveal that all three complexes exhibit similar tetranuclear face-shared defective double-cubane structure, having azido-, alk/phenoxido- and acetato-bridges. Magnetic susceptibility measurements on the complexes in the range of 300-2 K indicate ferromagnetic coupling between the metal ions. The slightly different magnetic behaviors observed are probably caused by subtle structural differences between the respective [Ni4O4N2] cores induced by ligand variation. (C) 2011 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.04.010