| 282717-24-2

• CAS: 282717-24-2
• 化学式: C₅₆H₄₇N₃OP₂Ru
• 分子量: 941.026
• InChiKey: RGTJXUPRUHADOW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  RuH₂(CO)(PPh₃)₃ 、 三苯基胍 以 甲苯 为溶剂， 以79%的产率得到
  参考文献：
  名称：

  N,N′,N″-Triphenylguanidinate(−1) complexes of ruthenium, osmium and iridium: synthesis and X-ray crystal structures

  摘要：

  N,N',N"-Triphenylguanidine (TpgH) reacts with [Ru(H)(2)(CO)(PPh3)(3)] in refluxing toluene and with [Os(H)(2)(CO)(PPh3)(3)] in refluxing o-xylene to yield the guanidinate(- 1) complexes [RuH(Tpg)(CO)(PPh3)(2)] (1) and [Os(Tpg)(2)(CO)(PPh3)] (2), respectively. The reaction of TpgH with [RuCl2(PPh3)(3)] in refluxing toluene affords a new route to the known complex [Ru(Tpg)(2)(CO)(PPh3)] (3). Finally the reaction of mer-[Ir(H)(3)(PPh3)(3)] with TpgH in refluxing toluene yields the iridium(III) dihydride complex [Ir(H)(2)(Tpg)(PPh3)(2)] (4). X-ray crystal structure determinations are reported for (1) and (4). (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(00)00046-3