cis-Cr(CO)4[N-[(2-pyridyl)methyliden]-α-aminonaphthalene] | 947490-94-0

• 英文名称: cis-Cr(CO)4[N-[(2-pyridyl)methyliden]-α-aminonaphthalene]
• 英文别名: cis-Cr(CO)4[α-NaiPy]
• CAS: 947490-94-0
• 化学式: C₂₀H₁₂CrN₂O₄
• 分子量: 396.322
• InChiKey: IJISXUDQRJDAKU-UZTHEFBISA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  (2-pyridyl)methylene(α-naphthyl)amine 、 六羰基铬 以 四氢呋喃 为溶剂， 以5%的产率得到cis-Cr(CO)4[N-[(2-pyridyl)methyliden]-α-aminonaphthalene]
  参考文献：
  名称：

  Group 6 tetracarbonyl complexes of N-[(2-pyridyl)methyliden]-α (or β)-aminonaphthalene: Spectral characterization, electrochemistry, solvatochromism and photophysical studies

  摘要：

  A new series of group 6 carbonyl complexes of N-[(2-pyridyl)methyliden]-alpha (or beta)-aminonaphthalene (alpha/beta-NaiPy) are described in this work. The complexes are formulated as cis-[M(CO)(4)(alpha/beta-NaiPy)] by elemental, mass and other spectroscopic data. The complexes show emission spectra at room temperature and their quantum yield lies between 0.4 and 0.5. All the complexes exhibit negative solvatochromism. Cyclic voltammetry shows metal centred oxidation and ligand reductions. (c) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2006.12.029