| 188398-10-9

• CAS: 188398-10-9
• 化学式: BF₄*C₂₀H₃₂As₄Cl₂Rh
• 分子量: 832.777
• InChiKey: FYXYEVYCNGADRR-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  tetrafluoroboric acid 、 氯化铑(三水) 、 1,2-亚苯基双(二甲基砷化氢) 以 乙醇 、 水 为溶剂， 以70%的产率得到
  参考文献：
  名称：

  Synthesis and spectroscopic studies of trans and cis rhodium(III) complexes of o-C6H4(PMe2)2 and o-C6H4(AsMe2)2. Crystal structures of trans-[Rh{0-C6H4(PMe2)2}2Cl2]Cl and [Rh{o-C6H4(AsMe2)2}2I2]BF4

  摘要：

  The rhodium(III) complexes trans-[Rh(L-L)(2)X(2)](+) [L-L = o-C6H4(PMe(2))(2) or o-C6H4(AsMe(2))2, X = Cl, Br or I] have been prepared from RhX(3) . nH(2)O and L-L, and converted to the cis-[Rh(L-L)(2)X(2)](+) by sequential treatment with Li2CO3 and HX. Both series of compounds have been characterized by analysis, UV-vis and multinuclear (H-1, P-31 {H-1} and Rh-103) NMR spectroscopy. The trends in the Rh-103 chemical shifts with L-L, X and stereochemistry are discussed. The crystal structures of trans-[Rh{o-C6H4(PMe(2))(2)}Cl-2(2)]Cl and trans-[Rh{o-C6H4(AsMe(2))(2)}I-2(2)]BF4 have been determined. Copyright (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(96)00406-8