[(Me2C(C5H4)(fluorenyl))HfMe(NMe2Ph)](1+) | 1079441-00-1

• 英文名称: [(Me2C(C5H4)(fluorenyl))HfMe(NMe2Ph)](1+)
• CAS: 1079441-00-1
• 化学式: C₃₀H₃₂HfN
• 分子量: 585.081
• InChiKey: RXAURUZTLTZNGA-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  (Me2C(C5H4)(9-fluorenyl))HfMe2 、 N,N-二甲基苯铵四(五氟苯基)硼酸盐 以 氘代甲苯 为溶剂， 生成 [(Me2C(C5H4)(fluorenyl))HfMe(NMe2Ph)](1+) 、 [((Me2C(C5H4)(fluorenyl))HfMe)2(μ-Me)](1+)
  参考文献：
  名称：

  Structural Characterization of a Cationic Zirconocene Dimethylaniline Complex and Related Catalytically Relevant Species

  摘要：

  We report the first crystallographically characterized dimethylaniline complex of a group 4 metallocene. [(IPCF)-ZrMe(NMe2Ph)][B(C6F5)(4)] shows strongly coordinated NMe2Ph which does not interchange in solution. DFT calculations suggest that the Zr-N bond is 23 kJ mol(-1) stronger than the Zr-Me-Zr bond in [{(IPCF)ZrMe}(2)(mu-Me)][MeB(C6F5)(3)], the structure of which is also reported (IPCF=Me2C(C5H4)(fluorenyl)).

  DOI：

  10.1021/om800783h