[(η5-C5Me5)2Ir2(μ-H)2(μ-amide)](tetraphenylborate) | 1309476-54-7

• 英文名称: [(η5-C5Me5)2Ir2(μ-H)2(μ-amide)](tetraphenylborate)
• CAS: 1309476-54-7
• 化学式: C₂₀H₃₄Ir₂N*C₂₄H₂₀B
• 分子量: 992.17
• InChiKey: GELXXKPUCRJFMV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [(η5-C5Me5)2Ir2(μ-H)(μ-imide)](tetraphenylborate)*CH2Cl2 、 氢气 以 二氯甲烷 为溶剂， 以29%的产率得到[(η5-C5Me5)2Ir2(μ-H)2(μ-amide)](tetraphenylborate)
  参考文献：
  名称：

  H–H and N–H Bond Cleavage of Dihydrogen and Ammonia with a Bifunctional Parent Imido (NH)-Bridged Diiridium Complex

  摘要：

  Hydrogenation and protonation of parent imido complexes have attracted much attention in relation to industrial and biological nitrogen fixation. The present study reports the structure and properties of the highly unsaturated diiridium parent imido complex [(Cp*Ir)(2)-(mu(2)-H)(mu(2)-NH)](+) derived from deprotonation of a parent amido complex. Because of the Lewis acid-Bronsted base bifunctional nature of the metal-NH bond, the parent imido complex promotes heterolysis of H-2 and deprotonative N-H cleavage of ammonia to afford the corresponding parent amido complexes under mild conditions.

  DOI：

  10.1021/ja203538b