[(η5-C5Me5)(CO)2Fe]2(μ-CH=CHCH=CH) | 599148-25-1

• 英文名称: [(η5-C5Me5)(CO)2Fe]2(μ-CH=CHCH=CH)
• CAS: 599148-25-1
• 化学式: C₂₈H₃₄Fe₂O₄
• 分子量: 546.27
• InChiKey: ZBCDBAYLNRNQJX-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  [(η5-C5Me5)(CO)2Fe]2(μ-CH=CHCH=CH) 、 1,2-双(二苯基膦)乙烷 以 四氢呋喃 为溶剂， 以40%的产率得到[(η5-C5Me5)(dppe)2Fe]2(μ-CH=CHCH=CH)
  参考文献：
  名称：

  Intermetal Coupling in [(η⁵-C₅R₅)Fe(dppe)]₂(μ-CHCHCHCH) and in Their Dicationic and Monocationic Mixed-Valence Forms

  摘要：

  The butadienediyl-bridged complexes [(eta(5)-C5R5)Fe(dppe)](2)(mu-CH=CHCH=CH) (R = H, Me) and their radical cationic and dicationic forms have been prepared and characterized by cyclic voltammetry, electronic spectroscopy (UV-vis and near-IR), EPR, and X-ray crystallography (R = Me). Comparisons with each other and with the literature complexes [(eta(5)C(5)H(5))Fe(dppm)](2)(mu-CH=CHCH=CH), [(eta(5)-C5Me5)Fe(dppe)](2)(mu-C=CC=C), and [(eta(5)-C5Me5)Fe(dppe)](2)(mu-C(OMe)=CHCH=C(OMe)) have allowed for systematic evaluation of several structural variations (C5H5 VS C5Me5, dppm vs dppe, mu-CH=CHCH=CH vs mu-C=CC=C, and mu-CH=CHCH=CH Vs mu-C(OMe)=CHCH=C(OMe)) and their effects on spectra and electronic intermetal coupling. Some of the structural changes have opposite effects on H-ab, the effective coupling parameter, and K-c, the comproportionation constant. The data for the mixed-valence cations are most consistent with electronic delocalization.

  DOI：

  10.1021/om0300979
• 作为产物：
  描述：

  [(η5-C5Me5)(CO)2Fe]2(μ-trans-3,4-cyclobutenediyl) 以 四氢呋喃 为溶剂， 以65%的产率得到[(η5-C5Me5)(CO)2Fe]2(μ-CH=CHCH=CH)
  参考文献：
  名称：

  Intermetal Coupling in [(η⁵-C₅R₅)Fe(dppe)]₂(μ-CHCHCHCH) and in Their Dicationic and Monocationic Mixed-Valence Forms

  摘要：

  The butadienediyl-bridged complexes [(eta(5)-C5R5)Fe(dppe)](2)(mu-CH=CHCH=CH) (R = H, Me) and their radical cationic and dicationic forms have been prepared and characterized by cyclic voltammetry, electronic spectroscopy (UV-vis and near-IR), EPR, and X-ray crystallography (R = Me). Comparisons with each other and with the literature complexes [(eta(5)C(5)H(5))Fe(dppm)](2)(mu-CH=CHCH=CH), [(eta(5)-C5Me5)Fe(dppe)](2)(mu-C=CC=C), and [(eta(5)-C5Me5)Fe(dppe)](2)(mu-C(OMe)=CHCH=C(OMe)) have allowed for systematic evaluation of several structural variations (C5H5 VS C5Me5, dppm vs dppe, mu-CH=CHCH=CH vs mu-C=CC=C, and mu-CH=CHCH=CH Vs mu-C(OMe)=CHCH=C(OMe)) and their effects on spectra and electronic intermetal coupling. Some of the structural changes have opposite effects on H-ab, the effective coupling parameter, and K-c, the comproportionation constant. The data for the mixed-valence cations are most consistent with electronic delocalization.

  DOI：

  10.1021/om0300979