[(ppy)₂Ir(dcbpy)]⁺•PF₆^- | 1020085-82-8

• 英文名称: [(ppy)₂Ir(dcbpy)]⁺•PF₆^-
• 英文别名: [(2-phenylpyridine)₂Ir(2,2'-bipyridine-4,4'-dicarboxylic acid)]⁺•PF₆^-；Ir(ppy)₂(H₂dcbpy)PF₆；Ir(2-phenylpyridine)₂(4,4′-dicarboxy-2,2′-bipyridine)PF₆；[Ir(dcb)(ppy)₂][PF₆]；[Ir(2,2'-bipyridine)₂(2,2’-bipyridyl-4,4’-dicarboxylic acid)][PF₆]；iridium(III) [bis(C,N-2-phenylpyridine)-N,N-4,4'-dicarboxy-2,2'-bipyridine] hexafluorophosphate；bis(phenylpyridine)(2,2'-bipyridine-4,4'-dicarboxylic acid)iridium(III) hexafluorophosphate；[Ir(bpy)₂(dcbH₂)][PF₆]；[Ir(dcb)(2-phenylpyridine)₂][PF₆]；[Ir(2-phenylpyridine-H)2(4,4'-diethoxycarbonyl-2,2'-bipyridine)]PF6；[Ir(2-phenylpyridine(-1H))2(4,4'-dicarboxy-2,2'-bipyridine)]PF6
• CAS: 1020085-82-8
• 化学式: C₃₄H₂₄IrN₄O₄*F₆P
• 分子量: 889.773
• InChiKey: ZEKUPISTEKIHNO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  sodium hydroxide 、 [(ppy)₂Ir(dcbpy)]⁺•PF₆^- 以 水 为溶剂， 反应 2.0h， 以96%的产率得到
  参考文献：
  名称：

  Water-soluble cyclometalated Ir(iii) complexes as carrier-free and pure nanoparticle photosensitizers for photodynamic therapy and cell imaging

  摘要：

  首次提供了一种简便的策略，以获得不带载体和纯净的纳米粒子光敏剂，用于光动力疗法和细胞成像，其为水溶性环金属Ir(iii)配合物。

  DOI：

  10.1039/d0dt02584d
• 作为产物：
  描述：

  六氟磷酸钾 、 2,2'-联吡啶-4,4'-二甲酸 、 [iridium(III)(μ-chloro)(2-phenylpyridine)2]2 以 甲醇 、 二氯甲烷 为溶剂， 反应 4.75h， 以85%的产率得到[(ppy)₂Ir(dcbpy)]⁺•PF₆^-
  参考文献：
  名称：

  Water-soluble cyclometalated Ir(iii) complexes as carrier-free and pure nanoparticle photosensitizers for photodynamic therapy and cell imaging

  摘要：

  首次提供了一种简便的策略，以获得不带载体和纯净的纳米粒子光敏剂，用于光动力疗法和细胞成像，其为水溶性环金属Ir(iii)配合物。

  DOI：

  10.1039/d0dt02584d

文献信息

• Four new lead(<scp>ii</scp>)–iridium(<scp>iii</scp>) heterobimetallic coordination frameworks: synthesis, structures, luminescence and oxygen-sensing properties
  作者：Yi-Ting Chen、Chun-Yen Lin、Gene-Hsiang Lee、Mei-Lin Ho

  DOI：10.1039/c4ce02457e

  日期：——

  Crystalline lead(ii)–iridium(iii) heterobimetallic coordination frameworks were prepared and characterized, and one was mixed with C480 to form a ratiometric oxygen sensor for the determination of oxygen in real gas.

  结晶铅（II）-铱（III）异双金属配位框架已制备并表征，其中一种与C480混合形成了比例氧气传感器，用于测定真实气体中的氧气。
• Synthesis, structure and oxygen-sensing properties of Iridium(iii)-containing coordination polymers with different cations
  作者：Mei-Lin Ho、Yi-An Chen、Tsai-Chen Chen、Pei-Jen Chang、Yi-Ping Yu、Kum-Yi Cheng、Chien-Hung Shih、Gene-Hsiang Lee、Hwo-Shuenn Sheu

  DOI：10.1039/c2dt11473a

  日期：——

  Four iridium(III)-containing coordination polymers 1–4 using Ir(ppy)2(H2dcbpy)PF6 (L-H2, ppy = 2-phenylpyridine, H2dcbpy = 4,4′-dicarboxy-2,2′-bipyridine) as the bridging ligand, [ZnL2]·3DMF·5H2O (1), [CdL2(H2O)2]·3DMF·6H2O (2), [CoL2(H2O)2]·2DMF·8H2O (3) and [NiL2(H2O)2]·3DMF·6H2O (4), have been synthesized and structurally characterized. The emissions from 1–4 are ascribed to a metal-to-ligand charge transfer transition (MLCT). The absolute emission quantum yields for 1–4 in single crystals were measured in air to be 0.274, 0.193, 0.001 and 0.002, respectively. The noteworthy oxygen-sensing properties of 1–4 as well as L-H2 in a single crystal were also evaluated. The Stern–Volmer quenching constant, KSV values, of 1–4 and L-H2 can be deduced to be 0.834, 2.820, 1.328, 1.111 and 2.476, respectively. The results show promising KSV values (e.g.2) that are competitive or even larger than those of many known Ir-complexes. Moreover, the short response time (e.g. compound 2) and recovery times toward oxygen of 1–4 have been measured in their single crystal forms. The reversibility experiments for 1–4 were carried out for seven repeated cycles. As a result, >75% recovery of intensity for 1 and 2 on each cycle demonstrates a high degree of reproducibility during the sensing process. It should be noted that iridium(III)-containing coordination polymers with high emission intensity and notable oxygen sensing properties are obscure, especially in the single crystal form. This, in combination with its fine reversibility, leads to success in single crystal oxygen recognition based on photoluminescence imaging. The detection limit could be 0.50% for gaseous oxygen. Moreover, the temperature effect of compound 2 in a single crystal upon application as an oxygen sensor was expected.

  以 Ir(PY)2(H2dcbpy)PF6（L-H2，PY = 2-苯基吡啶，H2dcbpy = 4,4′-二羧基-2,2′-联吡啶）为桥接配体的四种含铱(III)配位聚合物 1-4、合成了[ZnL2]-3DMF-5 （1）、[CdL2(H2O)2]-3DMF-6 （2）、[CoL2( )2]-2DMF-8 （3）和[NiL2( )2]-3DMF-6 （4），并对它们进行了结构表征。1-4 的发射归因于金属到配体的电荷转移转变（MLCT）。在空气中测得的 1-4 单晶绝对发射量子产率分别为 0.274、0.193、0.001 和 0.002。此外，还评估了单晶中 1-4 和 L-H2 值得注意的氧传感特性。1-4 和 L-H2 的斯特恩-沃尔默淬火常数 KSV 值分别为 0.834、2.820、1.328、1.111 和 2.476。这些结果表明，KSV 值（例如 2）很有希望与许多已知的铱络合物相媲美，甚至更大。此外，还测量了 1-4 的单晶形式对氧气的短响应时间（如化合物 2）和恢复时间。1-4 的可逆性实验重复进行了七个周期。结果表明，1 和 2 在每个循环中的强度恢复率大于 75%，这表明传感过程具有很高的可重复性。值得注意的是，含铱(III)配位聚合物具有高发射强度和显著的氧传感特性，尤其是在单晶形式下，这种特性并不明显。这一点再加上其良好的可逆性，使得基于光致发光成像的单晶氧气识别取得了成功。对气态氧的检测限可达 0.50%。此外，化合物 2 在单晶中用作氧气传感器时的温度效应也在意料之中。
• Photoredox Catalysis Using Heterogenized Iridium Complexes**
  作者：Kelly L. Materna、Leif Hammarström

  DOI：10.1002/chem.202101651

  日期：2021.12.6

  Heterogenized iridium catalysts were synthesized to generate reusable, robust photoredox catalysts. The catalyst architecture, in nanopowder or thin film forms, was studied to see how it affected the catalytic performance on three different metal oxide surfaces. Reductive dehalogenation of bromoacetophenone to acetophenone was studied as the model photoredox reaction, and all catalysts showed successful

  合成了多相铱催化剂，以产生可重复使用的、坚固的光氧化还原催化剂。研究了纳米粉末或薄膜形式的催化剂结构，以了解它如何影响三种不同金属氧化物表面的催化性能。研究了溴苯乙酮还原脱卤生成苯乙酮作为模型光氧化还原反应，所有催化剂均成功生成了产物。人们发现 Al 2 O 3基催化剂是两种结构中最坚固且可重复使用的催化剂，至少有约 1000 次周转，可重复使用 3 次。
• Luminescent Cyclometalated Rh^III, Ir^III, and (DIP)₂Ru^II Complexes with Carboxylated Bipyridyl Ligands: Synthesis, X-ray Molecular Structure, and Photophysical Properties
  作者：Jenny B. Waern、Christophe Desmarets、Lise-Marie Chamoreau、Hani Amouri、Andrea Barbieri、Cristiana Sabatini、Barbara Ventura、Francesco Barigelletti

  DOI：10.1021/ic702327z

  日期：2008.4.1

  rhodium(III) and iridium(III) complexes of the general formula [M(ppy) 2(N (wedge)N)][PF 6], with N (wedge)N = Hcmbpy = 4-carboxy-4'-methyl-2,2'-bipyridine and M = Rh ( 1), Ir ( 2) and N (wedge)N = H 2dcbpy = 4,4'-dicarboxy-2,2'-bipyridine and M = Rh ( 3), Ir ( 4), were prepared in high yields and fully characterized. The X-ray molecular structure of the monocarboxylic iridium complex [Ir(ppy) 2(Hcmbpy)][PF

  通式[M（ppy）2（N（楔形）N）] [PF 6]的发光环金属化铑（III）和铱（III）配合物，N（楔形）N = Hcmbpy = 4-羧基-4' -甲基-2,2'-联吡啶和M = Rh（1），Ir（2）和N（楔形）N = H 2dcbpy = 4,4'-二羧基-2,2'-联吡啶和M = Rh（3 ）Ir（4）以高收率制备并充分表征。还确定了单羧酸铱配合物[Ir（ppy）2（Hcmbpy）] [PF 6]（2）的X射线分子结构。研究了这些化合物的光物理性质，结果表明，铑配合物1和3和铱配合物2和4的光致发光源自配体内电荷转移（ILCT）和金属至配体电荷转移/以配体为中心的MLCT / LC分别激发态。为了进行比较，一元和二元羧酸钌络合物[Ru（DIP）2（Hcmbpy）] [Cl] 2（5）和[Ru（DIP）2（H 2dcbpy）] [Cl] 2（6），其中DIP = 4，还制备了7-二苯基-1
• Enhanced Iridium Complex Electrochemiluminescence Cytosensing and Dynamic Evaluation of Cell-Surface Carbohydrate Expression
  作者：Hong Zhou、Yiying Yang、Chunxiang Li、Bing Yu、Shusheng Zhang

  DOI：10.1002/chem.201403470

  日期：2014.11.3

  between concanavalin A (Con A) and mannose, the novel nanoparticle was applied to an ultrasensitive electrochemiluminescence (ECL) in situ cytosensing strategy and the dynamic evaluation of cell‐surface carbohydrate expression. The ECL activity of the presented Con A@Au/Ir‐MSN nanoprobe was greatly enhanced by employing a functionalized nanoparticle and graphene nanomaterial with an increased surface area

  新制备的[（PPY）2的Ir（dcbpy）] + ⋅PF 6 -（ppy：2-苯基吡啶基; dcbpy：4,4'-二羧基-2,2'-联吡啶基）和金纳米粒子功能化的介孔二氧化硅纳米粒子（Au / Ir-MSN）。基于伴刀豆球蛋白A（Con A）和甘露糖之间的结合，该新型纳米颗粒被应用于超灵敏电致发光（ECL）原位细胞传感策略和细胞表面碳水化合物表达的动态评估。通过使用功能化的纳米粒子和石墨烯纳米材料，增加了表面积，同时提高了电极界面的电子转移效率，大大提高了所提出的Con A @ Au / Ir-MSN纳米探针的ECL活性。在最佳条件下，夹心型ECL细胞传感器在1.0×10 2到1.0×10的浓度范围内对K562细胞表现出线性响应6个 细胞mL -1，实现了单个细胞的低检测限。所提出的方法也可以成功地用于监测癌细胞中碳水化合物表达响应抑制剂引起的外部刺激的动态变化。