ferrocene carboxylic acid 2-cyclohexa-1,4-dienyl-ethyl ester | 681431-74-3

• 英文名称: ferrocene carboxylic acid 2-cyclohexa-1,4-dienyl-ethyl ester
• CAS: 681431-74-3
• 化学式: C₁₉H₂₀FeO₂
• 分子量: 336.214
• InChiKey: BVMLFXVJDNSLPX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  水合三氯化钌 、 ferrocene carboxylic acid 2-cyclohexa-1,4-dienyl-ethyl ester 以 乙醇 为溶剂， 以87%的产率得到[RuCl2(η6-C6H5(CH2)2OC(O)C5H4Fe(C5H5))]2
  参考文献：
  名称：

  Synthesis of a trinuclear cation [H3Ru3(Fc-arene)(C6Me6)2(O)]+ containing a ferrocenyl group tethered to an arene ligand

  摘要：

  Ferrocene carboxylic acid 2-cyclohexa-1,4-dienyl-ethyl ester (1) is prepared from ferrocene carboxylic acid and 2-cyclohexa-1,4-dienyl-ethanol. This diene reacts with RuCl3.nH(2)O in refluxing ethanol to afford quantitatively [Ru(Fc-arene)Cl-2](2) (2) (Fc-arene=ferrocene carboxylic acid phenethyl ester). The dinuclear complex 2 reacts with triphenylphosphine to give the mononuclear complex [Ru(Fc-arene)(PPh3)Cl-2] (3). The trinuclear arene-ruthenium cluster cation [H3Ru3(Fc-arene)(C6Me6)(2)(O)](+) (4) is synthesised from the dinuclear precursor [H3Ru2(C6Me6)(2)](+) and the mononuclear complex [Ru(Fc-arene)(H2O)(3)](2+) accessible from 2 in aqueous solution. The water-soluble trinuclear cluster cation 4 catalyses the hydrogenation of benzene to give cyclohexane under biphasic conditions. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(03)00273-1
• 作为产物：
  描述：

  二茂铁甲酸 、 1-(2'-hydroxyethyl)-1,4-cyclohexadiene 在 N,N-dicyclohexylcarbodiimide 、 4-(dimethylamino)pyridine 、 4-pyrrolidinopyridine 作用下， 以 二氯甲烷 为溶剂， 以94%的产率得到ferrocene carboxylic acid 2-cyclohexa-1,4-dienyl-ethyl ester
  参考文献：
  名称：

  Synthesis of a trinuclear cation [H3Ru3(Fc-arene)(C6Me6)2(O)]+ containing a ferrocenyl group tethered to an arene ligand

  摘要：

  Ferrocene carboxylic acid 2-cyclohexa-1,4-dienyl-ethyl ester (1) is prepared from ferrocene carboxylic acid and 2-cyclohexa-1,4-dienyl-ethanol. This diene reacts with RuCl3.nH(2)O in refluxing ethanol to afford quantitatively [Ru(Fc-arene)Cl-2](2) (2) (Fc-arene=ferrocene carboxylic acid phenethyl ester). The dinuclear complex 2 reacts with triphenylphosphine to give the mononuclear complex [Ru(Fc-arene)(PPh3)Cl-2] (3). The trinuclear arene-ruthenium cluster cation [H3Ru3(Fc-arene)(C6Me6)(2)(O)](+) (4) is synthesised from the dinuclear precursor [H3Ru2(C6Me6)(2)](+) and the mononuclear complex [Ru(Fc-arene)(H2O)(3)](2+) accessible from 2 in aqueous solution. The water-soluble trinuclear cluster cation 4 catalyses the hydrogenation of benzene to give cyclohexane under biphasic conditions. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(03)00273-1