| 916839-77-5

• CAS: 916839-77-5
• 化学式: C₁₂H₁₃N₅O₂
• 分子量: 259.268
• InChiKey: KPDDQIXNLCWEGF-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  在 氢溴酸 作用下， 生成 4-amino-1-methyl-5-(phenylcarbamoyl)-1H-1,2,4-triazolium bromide
  参考文献：
  名称：

  Phenylcarbamoylation of N-Acetyl-1,2,4-triazolium-4-aminides Revisited

  摘要：

  The reaction of N-acetyl-1,2,4-triazolium-4-aminides (I, i.e. 1Aa-d) with phenyl isocyanate affords ring functionalized products (4a-d) rather than linear adducts (II). Analogous compounds are obtained from the triazolium-1-aminide (1Ae) and the imidazolium congener (W). Twofold carbamoylation to give products of type (8) occurs on reaction of aminotriazolium salts (7A) in the presence of base. Azoliums having methyl at C(5)/(2) are inert throughout (B series).

  DOI：

  10.3987/com-06-10836
• 作为产物：
  描述：

  异氰酸苯酯 、 N-acetyl-1-methyl-1H-1,2,4-triazolium-4-aminide 以 氯仿 为溶剂， 反应 18.0h， 生成
  参考文献：
  名称：

  Phenylcarbamoylation of N-Acetyl-1,2,4-triazolium-4-aminides Revisited

  摘要：

  The reaction of N-acetyl-1,2,4-triazolium-4-aminides (I, i.e. 1Aa-d) with phenyl isocyanate affords ring functionalized products (4a-d) rather than linear adducts (II). Analogous compounds are obtained from the triazolium-1-aminide (1Ae) and the imidazolium congener (W). Twofold carbamoylation to give products of type (8) occurs on reaction of aminotriazolium salts (7A) in the presence of base. Azoliums having methyl at C(5)/(2) are inert throughout (B series).

  DOI：

  10.3987/com-06-10836