| 80303-37-3

• CAS: 80303-37-3
• 化学式: C₁₅H₁₂O₉Ru₃
• 分子量: 639.465
• InChiKey: SXNSPBIDKVTCLB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 在 氢气 作用下， 以 正辛烷 为溶剂， 生成 [(μ-H)₄Ru₄(CO)₁₂]
  参考文献：
  名称：

  Amadelli, Rossano; Bartocci, Carlo; Carassiti, Vittorio, Gazzetta Chimica Italiana, 1985, vol. 115, # 6, p. 337 - 342

  摘要：

  DOI：
• 作为产物：
  描述：

  在 氢气 作用下， 以 正辛烷 为溶剂， 生成 、
  参考文献：
  名称：

  Amadelli, Rossano; Bartocci, Carlo; Carassiti, Vittorio, Gazzetta Chimica Italiana, 1985, vol. 115, # 6, p. 337 - 342

  摘要：

  DOI：

文献信息

• Reaction of ethylene with [Ru3(CO)12] and the dynamic processes of [Ru3H2(CO)9(C2R2)](R = H, Me, and Et)
  作者：John Evans、Gregory S. McNulty

  DOI：10.1039/dt9810002017

  日期：——

  [Ru(CO)4(H2CCH2)] is rapidly formed during the reaction of [Ru3(CO)12] with ethylene. However, prolonged reflux yielded a mixture of products of which [Ru3H2(CO)9(C2R2)][(1), R = H; (2), R = Me; (3), R = Et], [Ru3H(CO)9(RCCHCEt)][(4), R = Me; (5), R = Et], and [Ru4(CO)12(MeCCMe)](6) have been identified. Complexes (1), (2), and (3) are all stereochemically non-rigid. Generation of an apparent symmetry

  在[Ru 3（CO）12 ]与乙烯反应期间，快速形成[Ru（CO）4（H 2 C CH 2）] 。然而，长时间的回流产生了产物的混合物，其[Ru 3 H 2（CO）9（C 2 R 2）] [（1），R = H; （2），R =我；（3），R = Et]，[Ru 3 H（CO）9（RCCHCEt）] [（4），R = Me；（5），R = Et]和[Ru 4（CO）12（MeCCMe）]（6）已被识别。配合物（1），（2）和（3）在立体化学上都是非刚性的。对于所有三种配合物，均观察到由氢化物迁移产生明显的对称平面（机理1）。氢化物位点在（2）和（3）中是等效的，发现己炔配合物（3）可能独立发生氢化物位点交换（机理2）和炔烃振荡（机理3）。乙炔烷基尺寸的增加也增加了交换过程的速率。
• Solid–gas reactions of metal carbonyl clusters. Hydrogenation of 1,4-cyclohexadiene and hex-3-yne in the presence of H4Ru4(CO)12, Ru3(CO)12 or Ru3(CO)3(μ-CO)(μ3-CO)(μ3-‖-C2Ph2)(η-C5H5)2
  作者：Daniela Campagnola、Mario Castiglioni、Walter Dastrù、Stefano Deabate、Roberto Giordano、Philip J King、Enrico Sappa

  DOI：10.1016/s0020-1693(97)05516-3

  日期：1997.10

  The clusters H4Ru4(CO)(12) (1), Ru-3(CO)(12) (2) and Ru-3(CO)(3)(mu-CO)(mu(3)-CO) (mu(3)-parallel to-C2Ph2)(eta C5H5)(2) (3), which are homogeneous hydrogenation catalysts for alkynes and cyclic dienes, have been investigated in solid-gas hydrogenation reactions. The clusters were deposited on porous glass discs in a new reaction vessel and reacted with the vapours of 1,4-cyclohexadiene or hex-3-yne and dihydrogen, giving monoenes selectively. The apparatus is easy to use and allows the collection and analysis of the gaseous phase with time; limitations are discussed, The reactions are catalytic, with low turnover numbers (TON). Sublimation of the clusters and of reaction products onto the glass walls of the apparatus, formation and recondensation of metal fragments and/or of metallacyclic derivatives were observed during the experiments, The behaviour of the clusters under solid-gas conditions was found to be similar to that under homogeneous conditions. Comparable organometallic intermediates or byproducts have been isolated suggesting that the same reaction pathways occur. This work shows for the first time that electronically saturated clusters in the solid state can react with mixtures of gases under relatively mild conditions.
• Paw, Witold; Lake, Charles H.; Churchill, Melvyn Rowen, Organometallics, 1995, vol. 14, # 8, p. 3768 - 3782
  作者：Paw, Witold、Lake, Charles H.、Churchill, Melvyn Rowen、Keister, Jerome B.

  DOI：——

  日期：——