| 368867-42-9

• CAS: 368867-42-9
• 化学式: C₁₂H₁₈N₆Ni*Cl₁₀Te₂
• 分子量: 914.735
• InChiKey: OMTAFLWXVRIFLV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  碲化氢 、 磺酰氯 、 镍 、 乙腈 以 乙腈 为溶剂， 以99%的产率得到
  参考文献：
  名称：

  Halogenation of tellurium by SO2Cl2. Formation and crystal structures of (H3O)[Te3Cl13]·1/2SO2, [(C4H8O)2H][TeCl5]·(C4H8O), [(Me2SO)2H]2[TeCl6], and [Ni(NCCH3)6][Te2Cl10]

  摘要：

  The halogenation of elemental tellurium with SO2Cl2 in various solvents has been investigated. (H3O)[Te3Cl13].1/2SO(2) (1) and [(C4H8O)(2)H][TeCl5].(C4H8O) (2) were obtained in CS2 and THF, respectively. When DMSO is added into the THF solution of tellurium and SO2Cl2, [(Me2SO)(2)H](2)[TeCl6] (3) is formed. In the acetonitrile solution tellurium and SO2Cl2 form [Ni(NCCH3)(6)][Te2Cl10] (4) in the presence of metallic nickel. All compounds 1-4 were characterized by Te-125 NMR and by Xray crystallography. The formation of the anions has been discussed. (C) 2002 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(02)00909-9