propargyl cymantrene | 1422755-47-2

• 英文名称: propargyl cymantrene
• CAS: 1422755-47-2
• 化学式: C₁₁H₇MnO₃
• 分子量: 242.113
• InChiKey: CKJSHKPJDAZHSU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  三羰基(η-环戊二烯基)合锰 、 3-溴丙炔 在 正丁基锂 、 copper(I) bromide dimethylsulfide complex 作用下， 以 四氢呋喃 、 正己烷 、 甲苯 为溶剂， 反应 2.67h， 以16%的产率得到propargyl cymantrene
  参考文献：
  名称：

  An Anodic Method for Covalent Attachment of Molecules to Electrodes through an Ethynyl Linkage

  摘要：

  Electroactive organometallic molecules have been covalently attached to electrode surfaces through an ethynyl linkage. The process takes advantage of ethynyl-based radicals generated by anodic oxidation of a lithio-activated terminal ethynyl group. Electrophores containing redox-active ferrocene, cymantrene, or cobaltocenium moieties have been deposited at the one-to-three monolayer level. Both metal-based and ligand-based chemical reactions have been carried out on the surface-modified systems.

  DOI：

  10.1021/ja312405h