| 1132812-66-8

• CAS: 1132812-66-8
• 化学式: C₃₀H₃₁ClN₂OPt
• 分子量: 666.122
• InChiKey: UDGNDRNXRYALTK-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 苯乙炔 在 KOH 、 CuI 作用下， 以 甲醇 、 二氯甲烷 为溶剂， 以71%的产率得到Pt(C₂C₆H₅)(C₆H₅C₅H₂NC₅H₄NC₆H₃OCH₂CH(CH₂CH₃)(CH₂)3CH₃)
  参考文献：
  名称：

  Influence of Alkoxyl Substituent on 4,6-Diphenyl-2,2′-bipyridine Ligand on Photophysics of Cyclometalated Platinum(II) Complexes: Admixing Intraligand Charge Transfer Character in Low-Lying Excited States

  摘要：

  A series of platinum 4,6-diphenyl-2,2'-bipyridine complexes (6-10) with alkoxyl substituent on the 6-phenyl ring have been synthesized and characterized, The influence of the alkoxyl substituent on the nature of the low-lying excited states, and thus the photophysical properties, have been systematically investigated spectroscopically and theoretically. Complexes 6-10 exhibit a broad low-energy charge-transfer absorption band from 400 to 500 nm, which shows weak negative solvatochromic effect. They all emit at about 590 nm in fluid solutions at room temperature, with the emission energy essentially independent of the nature of the monodentate ligand and the polarity of solvent. The excited-state lifetimes of 6 and 7 are much longer (similar to 460-570 ns) than those of their corresponding "alkoxyl free" analogues 12 and 13 (similar to 40-100 ns) in CH3CN. Additionally, the emission quantum yields of 7-9 in CH2Cl2 are quite high (0.15-0.21). Spectroscopic studies and Time-Dependent Density Functional Theory (TDDFT) calculations indicate that these unique photophysical properties are induced by the electron-donating ability of the alkoxyl substituent, which causes a mixture of the intraligand charge transfer (ILCT) with the metal-to-ligand charge transfer (MLCT)/ligand-to-ligand charge transfer (LLCT) in their low-lying excited states. Complexes 6-10 exhibit broad triplet transient difference absorption in the near-UV to the near-IR region, where reverse saturable absorption (RSA) could occur. Nonlinear absorption experiments at 532 nm for nanosecond laser pulses demonstrate that 6-9 are strong reverse saturable absorbers, while 10 exhibits weak RSA because of its larger ground-state absorption cross-section and its low triplet excited-state quantum yield.

  DOI：

  10.1021/ic801589q
• 作为产物：
  描述：

  potassium tetrachloroplatinate(II) 、 6-[4-(2-ethylhexyloxy)phenyl]-4-phenyl-2,2'-bipyridine 以 溶剂黄146 为溶剂， 以83%的产率得到
  参考文献：
  名称：

  6-芳基-2,2'-联吡啶与 PtII 配合物衍生物的合成作为潜在抗肿瘤药物

  摘要：

  采用 Kröhnke 方法制备了芳基-和二芳基-2,2'-联吡啶的新型 Pt II配合物，用于进一步合成吡啶衍生物。对 1D 和 2D NMR 光谱数据进行1 H 和13 C NMR 光谱中的信号分配。合成化合物对体外培养的人类细胞的抗肿瘤活性的初步筛选评估显示所选样品具有较高的生物学意义。实时荧光染色和聚合酶链反应显示，在所研究的化合物的作用下，细胞死亡通过细胞凋亡类型进行。

  DOI：

  10.1007/s11172-023-4094-5

文献信息

• Dinuclear platinum(ii) 4,6-diphenyl-2,2′-bipyridine complexes tethered by a rigid bridging ligand: synthesis and photophysics in solution and in LB film
  作者：Iswarya Mathew、Yunjing Li、Zhongjing Li、Wenfang Sun

  DOI：10.1039/c0dt00597e

  日期：——

  transfer) and 1π,π* transitions. Both complexes are emissive in solutions at room temperature and in glassy matrix at 77 K. The emitting state is tentatively assigned as 3MLCT for 1 and 3MLCT/3ILCT/3π,π* for 2 at room temperature. At 77 K, the emission observed for 1 is mainly from the emissive ground-state aggregates, which is concentration dependent; while in 2 the emission from the monomer dominates. Unlike

  两个双核 铂（II）4,6-二苯基-2,2'-联吡啶 （C ^ N ^ N）具有刚性桥联配体的配合物（1和2）顺式-1,2-双（二苯基膦基）乙烯合成和它们的光物理性质在溶液中进行了系统研究用于1和2以及在LB膜2。成它们相应的单核络合物相似，二者配合物表现出强烈1个π，π*吸收在可见光区域，这可能从混合茎UV区和宽的，中等吸收带1 MLCT（金属-配体电荷转移） ，1个ILCT（配体内电荷转移）和1个π，π*跃迁。两种络合物在室温下均在溶液中发光，在77 K时在玻璃状基质中发光。发射态暂定为1和3的3 MLCT。MLCT / 3 ILCT / 3 π，π*为2在室温下。在77 K时，观测到的1的发射主要来自基态的发射态聚集体，这与浓度有关；而在2中，单体的发射占主导地位。不像双核铂 具有柔性桥联配体的复合物 二苯基膦乙烷，室温下1和2的电子吸收和发射能量与它们的浓度无关，这表明这两种配合物具有固定的构象。另外，存在烷氧基