cis-[(4-phenylpyridine)(CO)3Re(μ-SC6H5)2Re(CO)(4-phenylpyridine)] | 1233959-95-9

• 英文名称: cis-[(4-phenylpyridine)(CO)3Re(μ-SC6H5)2Re(CO)(4-phenylpyridine)]
• 英文别名: cis-[(Phpy)(CO)3Re(μ-SC6H5)2Re(CO)(Phpy)]
• CAS: 1233959-95-9
• 化学式: C₄₀H₂₈N₂O₆Re₂S₂
• 分子量: 1069.22
• InChiKey: PNLZZDBFCSQAEM-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  4-苯基吡啶 、 十羰基二铼 、 二苯二硫醚 以 均三甲苯 为溶剂， 以36%的产率得到cis-[(4-phenylpyridine)(CO)3Re(μ-SC6H5)2Re(CO)(4-phenylpyridine)]
  参考文献：
  名称：

  One-pot synthesis of sulphur bridged dinuclear rhenium metallacycles via addition of S–S bond across Re–Re bond

  摘要：

  Oxidative addition of diaryl disulphides RSSR to low-valent transition metal carbonyl Re(2)(CO)(10) with monodendate pyridine ligands bring forth novel sulphur bridged neutral dinuclear rhenium metallacycles [L(CO)(3)Re(mu-SR)(2)Re(CO)(3)L] (1-9) (L = pyridine ligand, R = aryl group) under one pot reaction conditions. The Metallacycles 1-9 have been characterised by elemental analysis, NMR and IR and absorption spectral analysis. Molecular structures of 4, 8 and 9 were determined by crystallographic analysis and the structural studies reveal that pyridyl groups attached to metal centres exhibit cis conformation. (C) 2010 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2010.02.027