[IrCl(C2H4)(PiPr3)]2 | 221236-76-6

• 英文名称: [IrCl(C2H4)(PiPr3)]2
• CAS: 221236-76-6
• 化学式: C₂₂H₅₀Cl₂Ir₂P₂
• 分子量: 831.933
• InChiKey: JTACFBPQWQVLKS-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  triisopropylarsine 、 [IrCl(C2H4)(PiPr3)]2 以 苯 为溶剂， 以82%的产率得到
  参考文献：
  名称：

  铱 (I) 和铱 (III) 与三异丙基砷烷作为配体的配合物

  摘要：

  The ethene complex trans-[IrCl(C2H4) (ASiPr(3))(2)] (2), which was prepared from [IrCl(C2H4)(2)](2) and AsiPr(3), reacted with CO and Ph2CN2 by displacement of ethene to yield the substitution products trans-[IrCl(L) (ASiPr(3))(2)] (3: L = CO; 4: L = N-2) UV irradiation of 2 in the presence of acetonitrile gave via intramolecular oxidative addition the hydrido(vinyl) iridium(III) compound [IrHCl(CH=CH2)(CH3CN)(AsiPr(3))(2)] (5). The reaction of 2 with dihydrogen led under argon to the formation of the octahedral complex [IrH2Cl(C2H4)(AsiPr(3))(2)] (7), whereas from 2 under 1 bar H-2 the ethene-free compound [IrH2Cl(AsiPr(3))(2)] (6) was generated. Complex 6 reacted with ethene to afford 7 and with pyridine to give [IrH2Cl(py)(AsiPr(3))(2)] (8). The mixed arsane(phosphane)iridium(I) compound [IrCl(C2H4)(PiPr(3))-(AsiPr(3))] (11) was prepared either from the dinuclear complex [IrCl(C2H4)(PiPr(3))](2) (9) and AsiPr(3) or by ligand exchange from [IrCl(C2H4)(PiPr(3)) (SbiPr(3))] (10) und triisopropylarsane. The molecular structure of 5 was determined by X-ray crystallography.

  DOI：

  10.1002/1521-3749(200012)626:12<2457::aid-zaac2457>3.0.co;2-k