[Re(CO)3(N,N-bis(quinolinoyl)aminovaleric acid)]Br | 884589-14-4

• 英文名称: [Re(CO)3(N,N-bis(quinolinoyl)aminovaleric acid)]Br
• CAS: 884589-14-4
• 化学式: Br*C₂₈H₂₅N₃O₅Re
• 分子量: 749.635
• InChiKey: ZFXDKZZTWMVUKT-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  (NEt4)2[rhenium(I)(bromide)3(carbonyl)3] 、 5-(bis(quinoline-2-ylmethyl)ammonio) pentanoate 以 甲醇 为溶剂， 生成 [Re(CO)3(N,N-bis(quinolinoyl)aminovaleric acid)]Br
  参考文献：
  名称：

  A new bifunctional amino acid chelator targeting the glucose transporter

  摘要：

  The coupling reactions of D-glucosamine, 1,3,4,6-tetra-O-acetylglucosamine, and 4-aminophenyl-galactopyranosine with N,N-bis(quinolinoyl) aminovaleric acid (L1) provided a series of conjugates containing a potentially tridentate donor group terminus linked to a sugar moiety, L2', L2 and L3, respectively. Reactions of the ligands with [NEt4](2)[Re(CO)(3)Br-3] in refluxing methanol provided the rhenium complexes [Re(CO3)(L1)]Br (ReL1), [Re(CO)(3)(L2)]Br (ReL2), [Re(CO)(3)(L2')]Br (ReL2') and [Re(CO)(3)(L3)]Br (ReL3). The ligands and complexes were characterized by elemental analyses, H-1 and C-13 NMR, mass spectroscopy and, in the case of L1 and ReL1, by X-ray crystallography. The rhenium complexes exhibit fluorescence emissions with long lifetimes, large Stokes shifts, and moderate quantum yields. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.11.022