o-diphenylphosphinoferrocene sulfonic acid | 1334528-39-0

• 英文名称: o-diphenylphosphinoferrocene sulfonic acid
• CAS: 1334528-39-0
• 化学式: C₂₂H₁₉FeO₃PS
• 分子量: 450.278
• InChiKey: WFWLTUDUPQWADB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (N,N,N',N'-tetramethylethylenediamine)dimethylpalladium(II) 、 o-diphenylphosphinoferrocene sulfonic acid 以 四氢呋喃 为溶剂， 以52%的产率得到[(o-diphenylphosphinoferrocene sulfonate)Pd(methyl)]2(N,N,N'N'-tetramethylethylenediamine)
  参考文献：
  名称：

  o-Diarylphosphinoferrocene Sulfonate Palladium Systems for Nonalternating Ethene–Carbon Monoxide Copolymerization

  摘要：

  A series of ferrocene-derived o-diarylphosphino/sulfonate ligands were prepared. Treatment of the o-diphenylphosphinoferrocene sulfonic acid (2a) with (allyl)PdCl dimer and sodium carbonate as the base gave the corresponding chelate (Fc-O,P)Pd(pi-allyl) complex 7a (as a mixture of two isomers). In the presence of pyridine instead of Na2CO3 the analogous reaction yielded the square-planar (Fc-O,P)Pd(Cl)pyridine complex 8a. Both systems were characterized by X-ray diffraction. Reaction of the series of three differently -P(aryl)(2)-substituted (Fc-O,P)H ligands with PdMe2(tmeda) gave the respective (Fc-O,P)PdMe(pyridine) derivatives (11). All three examples 11a,b,c and one precursor complex, [(Fc-O,P)PdMe](2)(tmeda) (10a), were characterized by X-ray diffraction. The ligand system o-bis-(o-anisyl)phosphinoferrocene sulfonic acid (2b) formed an active catalyst for ethene/CO nonalternating copolymerization upon treatment with Pd(OAc)(2) in methanol. Up to ca. 25% extra ethene incorporation was obtained at an ethene/CO partial pressure ratio of ca. 10:1. This catalyst system and its equivalent derived from the preformed (Fc-O,P)PdMe(pyridine) precursor complex (11b) showed reasonable catalyst activities under these conditions.

  DOI：

  10.1021/om200628r
• 作为产物：
  描述：

  盐酸 、 正丁基锂 、 lithium o-ferrocene sulfonate 、 二苯基氯化膦 以 四氢呋喃 、 正己烷 为溶剂， 以44%的产率得到o-diphenylphosphinoferrocene sulfonic acid
  参考文献：
  名称：

  o-Diarylphosphinoferrocene Sulfonate Palladium Systems for Nonalternating Ethene–Carbon Monoxide Copolymerization

  摘要：

  A series of ferrocene-derived o-diarylphosphino/sulfonate ligands were prepared. Treatment of the o-diphenylphosphinoferrocene sulfonic acid (2a) with (allyl)PdCl dimer and sodium carbonate as the base gave the corresponding chelate (Fc-O,P)Pd(pi-allyl) complex 7a (as a mixture of two isomers). In the presence of pyridine instead of Na2CO3 the analogous reaction yielded the square-planar (Fc-O,P)Pd(Cl)pyridine complex 8a. Both systems were characterized by X-ray diffraction. Reaction of the series of three differently -P(aryl)(2)-substituted (Fc-O,P)H ligands with PdMe2(tmeda) gave the respective (Fc-O,P)PdMe(pyridine) derivatives (11). All three examples 11a,b,c and one precursor complex, [(Fc-O,P)PdMe](2)(tmeda) (10a), were characterized by X-ray diffraction. The ligand system o-bis-(o-anisyl)phosphinoferrocene sulfonic acid (2b) formed an active catalyst for ethene/CO nonalternating copolymerization upon treatment with Pd(OAc)(2) in methanol. Up to ca. 25% extra ethene incorporation was obtained at an ethene/CO partial pressure ratio of ca. 10:1. This catalyst system and its equivalent derived from the preformed (Fc-O,P)PdMe(pyridine) precursor complex (11b) showed reasonable catalyst activities under these conditions.

  DOI：

  10.1021/om200628r

文献信息

• Redox‐Controlled Olefin (Co)Polymerization Catalyzed by Ferrocene‐Bridged Phosphine‐Sulfonate Palladium Complexes
  作者：Min Chen、Bangpei Yang、Changle Chen

  DOI：10.1002/anie.201507274

  日期：2015.12.14

  interconversion between neutral and oxidized forms of palladium complexes containing ferrocene‐bridged phosphine sulfonate ligands was demonstrated. The activity of these palladium complexes could be controlled using redox reagents during ethylene homopolymerization, ethylene/methyl acrylate copolymerization, and norbornene oligomerization. Specifically in norbornene oligomerization, the neutral complexes

  证明了中性和氧化形式的含二茂铁桥联的膦磺酸盐配体的钯配合物之间的容易和可逆的相互转化。这些钯配合物的活性可以在乙烯均聚，乙烯/丙烯酸甲酯共​​聚和降冰片烯低聚过程中使用氧化还原试剂进行控制。特别是在降冰片烯低聚中，中性配合物根本没有活性，而氧化的配合物则表现出明显的活性。在中性和氧化形式之间原位切换导致降冰片烯低聚中有趣的“关闭”和“开启”行为。这项工作提供了控制烯烃聚合过程的新策略。