| 220061-60-9

• CAS: 220061-60-9
• 化学式: C₅₆H₁₂₀BaCu₆O₈
• 分子量: 1440.17
• InChiKey: VYLWORHQKIICIX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  3-戊醇,3-乙基-,铜(1+)盐 、 以 四氢呋喃 为溶剂， 以19%的产率得到
  参考文献：
  名称：

  Crystal structures of the Ba–Cu(I) alkoxides Ba4Cu6(O) (OCEt3)12 and BaCu6(OCEt3)8

  摘要：

  A single crystal of the Ba-Cu(I) oxo-alkoxide Ba4Cu6(O)(OCEt3)(12) (1) was isolated from the reaction of Ba2Cu4(OCEt3)(8) (2) with oxygen. Oxo-alkoxide 1 crystallizes in the cubic space group 123 with the four Pa atoms distributed tetrahedrally around the central oxide ion and six Cu(OCEt3)(2)(-) units bridging each Pa atom to the three others. The Ba-Cu(I) alkoxides [BaCu(OCEt3)(3)](n) (3) and BaCu6(OCEt3)(8) (4) were also synthesized. Crystals were not obtained for 3, but the easily crystallized 4 has two Cu-3(OCEt3)(4)(-) moieties coordinated to a central Pa atom, and disproportionates in solution to many products. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(98)00206-x