[(μ5-C5H4PPh2)Re(CO)3]AuCl | 1132793-47-5

• 英文名称: [(μ5-C5H4PPh2)Re(CO)3]AuCl
• CAS: 1132793-47-5
• 化学式: C₂₀H₁₄AuClO₃PRe
• 分子量: 751.93
• InChiKey: RCEHLASMAVACAK-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  (tetrahydrothiophene)gold(I) chloride 、 tricarbonyl(η5-diphenylphosphinocyclopentadienyl)rhenium 以 二氯甲烷 为溶剂， 以90%的产率得到[(μ5-C5H4PPh2)Re(CO)3]AuCl
  参考文献：
  名称：

  Heterobimetallic Re–Pd, Re–Au and Re–Cu complexes derived from diphenylphosphino cyrhetrene: Synthesis and X-ray structure

  摘要：

  Diphenylphosphinecyrhetrene ligand (eta(5)-C5H4PPh2)Re(CO)(3) (1) reacts with 1 equiv. of PdCl2(NCPh)(2) to form, after workup, the square-planar trans-[(eta(5)-C5H4PPh2)Re(CO)(3)]PdCl2(NCMe) (2). Similarly, reaction of 1 with (tetra hydrothiophene)AuCl produces, in excellent yield, the bimetallic complex [(eta(5)-C5H4PPh2)Re(CO)(3)]AuCl (3) with a linear P-Au-Cl moiety. From the reaction of 2 equiv. of 1 with CuBr(SMe2) the planar-trigonal complex [(eta(5)-C5H4PPh2)Re(CO)(3)](2)CuBr (4) was obtained. P-31 NMR and X-ray crystallography demonstrate, for the three cases, that (eta(5)-C5H4PPh2)Re(CO)(3) acts as a monodentate ligand. The structural parameters of the bimetallic complexes are compared with related diphenylphosphinoferrocene metal complexes, described in the literature. (c) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2008.10.038