tricarbonyl((6-9-η)-2-oxo-1,1,3,3-tetramethyl-8-methoxyspiro[4.5]deca-6,8-diene)iron | 174195-13-2

• 英文名称: tricarbonyl((6-9-η)-2-oxo-1,1,3,3-tetramethyl-8-methoxyspiro[4.5]deca-6,8-diene)iron
• CAS: 174195-13-2
• 化学式: C₁₈H₂₂FeO₅
• 分子量: 374.217
• InChiKey: YJGBWSJJUNUWLT-FKOXPEIHSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  tricarbonyl[(1-4-η)-2-methoxy-5-methylenecyclohexa-1,3-diene]iron 、 2,4-二溴-2,4-二甲基-3-戊酮 在 diiron nonacarbonyl 作用下， 以 苯 为溶剂， 以86%的产率得到tricarbonyl((6-9-η)-2-oxo-1,1,3,3-tetramethyl-8-methoxyspiro[4.5]deca-6,8-diene)iron
  参考文献：
  名称：

  1,3-Dipolar Cycloaddition to Tricarbonyl[(1−4-η)-2- methoxy-5-methylenecyclohexa-1,3-diene]iron:  Rapid Construction of a Spiro[4.5]decane System

  摘要：

  Tricarbonyl[(1-4-eta)-2-methoxy-5-methyl-enecyclohexa-1,3-diene]iron (1) undergoes 1,3-dipolar cycloaddition reaction regio-, stereo-, and chemoselectively at its exocyclic double bond, yielding a spiro[4.5]-decane system. Reactive 1,3-dipoles with low-lying LUMO's such as nitrile oxides, ozone, diazoacetate, and oxoallyl cation participate well in cycloaddition to give isoxazole, ketone, pyrazoline, and cyclopentanone adducts, respectively. The complex 1 can be viewed as the synthetic equivalent of synthon 2 and has been illustrated for the first time as a versatile synthetic intermediate.

  DOI：

  10.1021/om950770x