[2,6-bis(benzylaminothiocarbonyl-κS)phenyl-κC1]chloropalladium(II) dimethylacetamide solvate | 1292297-85-8

• 英文名称: [2,6-bis(benzylaminothiocarbonyl-κS)phenyl-κC1]chloropalladium(II) dimethylacetamide solvate
• CAS: 1292297-85-8
• 化学式: C₄H₉NO*C₂₂H₁₉ClN₂PdS₂
• 分子量: 604.533
• InChiKey: HMZISRJNAKGQSA-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  N,N-二甲基乙酰胺 、 [2,6-bis(benzylaminothiocarbonyl-κS)phenyl-κC1]chloropalladium(II) 以 N,N-二甲基乙酰胺 为溶剂， 生成 [2,6-bis(benzylaminothiocarbonyl-κS)phenyl-κC1]chloropalladium(II) dimethylacetamide solvate
  参考文献：
  名称：

  Enhancement of the photoluminescence of a thioamide-based pincer palladium complex in the crystalline state

  摘要：

  A thioamide-based pincer Pd complex, [2,6-bis(benzylaminothiocarbonyl-kappa S) phenyl-kappa C-1] chloropalladium(II), was crystallized from different solvents. The structure of the complex in the solid state depends on hydrogen bonding interactions of cocrystallized solvent molecules with the metal complex in the crystal. The arrangement affects the intensity of the photoluminescence from the crystals. Strong emission was observed from the crystal having a densely packed arrangement of the complex, whereas the solutions and powders of the complex did not exhibit emission. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2010.12.037