| 593247-89-3

• CAS: 593247-89-3
• 化学式: BF₄*C₂₄H₂₂FeN₂O₂P
• 分子量: 544.076
• InChiKey: KJSXDMUZNASLDB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  在 (CH₃)3NO*2H₂O 作用下， 以 二氯甲烷 为溶剂， 以35%的产率得到C₅H₅Fe(CO)P(C₆H₅)2C₃HN₂(CH₃)2⁽¹⁺⁾*BF₄^(1-)=C₅H₅Fe(CO)P(C₆H₅)2C₃HN₂(CH₃)2BF₄
  参考文献：
  名称：

  New stable cyclopentadienyl iron(II) complexes containing 3,5-dimethylpyrazolyl phosphine

  摘要：

  Very stable complexes of general formula [FeCp(CO)(x)Ph2P(Me(2)Pz)]BF4, where x = 1(1)-2(2) were prepared by room temperature reaction of the 3,5-dimethylpyrazolylphosphine ligand with [Fe-2(CO)(2)(C5H5)(2)]. When [FeCp(CO)(2)Ph2P(Me(2)Pz)]BF4 (1) was treated with (CH3)(3)NO.2H(2)O, one coordinated CO was lost and complex 2 was formed. H-1-, C-13 and P-31-NMR spectra supported a structure of 2 with pyrazolyl ligand chelated to iron forming a four-membered metallocycle. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(03)00261-4
• 作为产物：
  描述：

  cyclopentadienyl iron(II) dicarbonyl dimer 、 ferrocenium(III) tetrafluoroborate 、 diphenyl(3,5-dimethylpyrazolyl)phosphine 以 二氯甲烷 为溶剂， 以60%的产率得到
  参考文献：
  名称：

  New stable cyclopentadienyl iron(II) complexes containing 3,5-dimethylpyrazolyl phosphine

  摘要：

  Very stable complexes of general formula [FeCp(CO)(x)Ph2P(Me(2)Pz)]BF4, where x = 1(1)-2(2) were prepared by room temperature reaction of the 3,5-dimethylpyrazolylphosphine ligand with [Fe-2(CO)(2)(C5H5)(2)]. When [FeCp(CO)(2)Ph2P(Me(2)Pz)]BF4 (1) was treated with (CH3)(3)NO.2H(2)O, one coordinated CO was lost and complex 2 was formed. H-1-, C-13 and P-31-NMR spectra supported a structure of 2 with pyrazolyl ligand chelated to iron forming a four-membered metallocycle. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(03)00261-4