AlMe2(Ph2-AFA) | 1262801-83-1

• 英文名称: AlMe2(Ph2-AFA)
• 英文别名: AlMe2(bis(N,N'-phenyl)-6-aminofulvene-2-aldimine)
• CAS: 1262801-83-1
• 化学式: C₂₁H₂₂AlN₂
• 分子量: 329.401
• InChiKey: SBYYCVWSHIWJSV-YDGOCWRKSA-N

反应信息

• 作为产物：
  描述：

  N,N'-diphenyl-6-aminopentafulvene-1-aldimine 、 三甲基铝 以 四氢呋喃 、 甲苯 为溶剂， 以49%的产率得到AlMe2(Ph2-AFA)
  参考文献：
  名称：

  Synthesis and Structure of 6-Aminofulvene-2-aldiminate Complexes

  摘要：

  We report here a synthetic route to bis(N,N'-aryl)-6-aminofulvene-2-aldimine (AFA) ligand systems, specifically Ph-2-AFAH and Dip(2)-AFAH. The synthesis and structural characterization of a series of Cu(I) complexes [(Ph-2-AFA)-Cu(CNPh)(2)] (2), [(Ph-2-AFA)Cu(CN'Pr)] (3), and [(Dip(2)-AFA)Cu(CN'Pr)] (4), from the reaction of the corresponding lithiated AFA systems with Cu-Cl derivatives are reported; notably in the case of [(Ph-2-AFA)Cu(CNPh)(2)] studies have revealed the existence of two structural isomers (2a and 2b), both of which can be isolated and structurally characterized. Density functional theory (DFT) calculations suggest that the two crystal forms are comparatively close in energy, and geometry optimization reveals a convergence of these two forms to a geometry that more closely resembles the solid-state structure of isomer 2b, having a CH center dot center dot center dot pi interaction. The reactions of the AFA compounds Ph-2-AFAH and Dip(2)-AFAH with ZnMe2 and AlMe3 have also been investigated, and the results of these reactions are described here.

  DOI：

  10.1021/ic101524b