| 185758-71-8

• CAS: 185758-71-8
• 化学式: C₁₁H₁₄FeO₃
• 分子量: 250.077
• InChiKey: KGAJNSILWOOZAU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  CpFe(CO)2(η1-CH2CH2CH=CH2) 、 水 在 sodium hydroxide 、 硼烷四氢呋喃络合物 、 双氧水 作用下， 以 四氢呋喃 、 水 为溶剂， 以70%的产率得到
  参考文献：
  名称：

  The synthesis and characterisation of a new series of ω-hydroxy-alkyl complexes of iron

  摘要：

  omega-Hydroxy-alkyl compounds of the type, [Fe(eta(5)-C5R5){(CH2)(n)CH2OH}(CO)(2)] (R=H and Me, n =2-5, 7) were prepared by the oxidative hydroboration of the appropriate eta(1)-alkenyl compounds of the general formula, [Fe(eta(5)-C5R5){(CH2)(n-1)CH=CH2}(CO)(2)]. All new compounds were characterised by infrared, H-1 and C-13 NMR spectroscopy as well as mass spectrometry. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(99)00252-1

文献信息

• Reactivity studies on some η1-alkenyl complexes of iron
  作者：Leone Hermans、Selwyn F. Mapolie

  DOI：10.1016/s0277-5387(96)00295-1

  日期：1997.1

  The eta(1)-alkenyl complexes [eta(5)-C5H5(CO)(2)Fe(CH2)(n)CH=CH2] (n = 2 and 3) have been prepared by the reaction of Na[eta(5)-C5H5(CO)(2)Fe] with 4-bromo-1-butene and 5-bromo-1-pentene respectively. The reactivity of the sigma-olefin complexes in hydrogenation, hydroboration and hydroformylation reactions are reported as are reactions with Lewis acids such as TiCl4 and the electrophile HCl. Copyright (C) 1996 Elsevier Science Ltd