(η(6)-anisole)tricarbonyl manganese hexafluorophosphate | 57812-97-2

• 英文名称: (η(6)-anisole)tricarbonyl manganese hexafluorophosphate
• 英文别名: (η6-anisole)tricarbonylmanganese(I) hexafluorophosphate；tricarbonyl(η(6)-anisole)manganese hexafluorophosphate；(anisole)manganese tricarbonyl hexafluorophosphate
• CAS: 57812-97-2
• 化学式: C₁₀H₈MnO₄*F₆P
• 分子量: 392.073
• InChiKey: OGYVZUSHQNEIDP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (η(6)-anisole)tricarbonyl manganese hexafluorophosphate 在 三异丙氧基硼氢化钾 作用下， 以 四氢呋喃 为溶剂， 以65.3%的产率得到2-methoxycyclohexadienylmanganese tricarbonyl
  参考文献：
  名称：

  通过锰-氢-碳键桥连的环己烯基锰三羰基配合物，锰介导的芳烃还原为环己-1,3-二烯

  摘要：

  阳离子三羰基锰二甲苯、邻二甲苯、二联苯和苯甲醚环己二烯-1,3 自由体阳离子转化练习曲

  DOI：

  10.1021/ja00327a015

文献信息

• Reactivity of Metallophosphide Anions with Electrophilic (Arene)tricarbonylmetal Complexes
  作者：Virginie Comte、Jean Philippe Tranchier、Françoise Rose‐Munch、Eric Rose、Danièle Perrey、Philippe Richard、Claude Moïse

  DOI：10.1002/ejic.200200531

  日期：2003.5

  Reaction of metallophosphide anions [(CO)xM′PPh2]− (M′ = Cr, Fe) with neutral tricarbonyl(η6-fluoroarene)chromium and cationic (η6-arene)tricarbonylmanganese complexes give rise to the formation of dinuclear complexes. These complexes are obtained either by substitution of the fluoride anion in the (arene)chromium complexes, or by addition to the ring in the (arene)manganese complexes. The X-ray structure

  金属磷化物阴离子 [(CO)xM'PPh2]- (M' = Cr, Fe) 与中性三羰基（η6-氟芳烃）铬和阳离子（η6-芳烃）三羰基锰配合物反应形成双核配合物。这些配合物是通过取代（芳烃）铬配合物中的氟阴离子，或通过添加到（芳烃）锰配合物中的环上而获得的。获得了一种均二金属 (Cr-Cr) 配合物的 X 射线结构，并与其溶液结构进行了比较。(© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)
• Reduction and alkylation of (η6-arene)tricarbonylmanganese complexes using alkyl-substituted coenzyme NADH models
  作者：Lidong Cao、Li Zheng、Qiliang Huang

  DOI：10.1016/j.jorganchem.2014.06.021

  日期：2014.10

  direct tert-butyl group transfer was observed between t-BuBNAH and (η6-arene)Mn(CO)3+ complexes in reflux acetonitrile without a radical initiator, and the corresponding tert-butyl radical addition products were achieved. The substituents on the aromatic ring significantly influence the reactivity and chemoselectivity. The electron-withdrawing group helps to promote the reactions. The radical inhibition

  直接叔之间观察丁基基团转移被吨-BuBNAH和（η 6 -arene）的Mn（CO）3个+在回流的乙腈配合物没有自由基引发剂，和相应的叔丁基分别实现自由基的加成产物。芳环上的取代基显着影响反应性和化学选择性。吸电子基团有助于促进反应。自由基抑制实验表明，该反应可能是由单电子转移引发的自由基链过程。
• Addition of Stabilized Carbanions to Cationic (η6-Arene)tricarbonylmanganese Complexes: Syntheses of Homo (Mn–Mn) and Hetero (Mn–Cr) Dinuclear Complexes
  作者：Eric Rose、Claudine Le Corre-Susanne、Françoise Rose-Munch、Christophe Renard、Vanessa Gagliardini、Fatima Teldji、Jacqueline Vaissermann

  DOI：10.1002/(sici)1099-0682(199903)1999:3<421::aid-ejic421>3.0.co;2-0

  日期：1999.3
• Indium-Mediated Alkyl Radical Addition to (η⁶-Arene)tricarbonylmanganese Complexes in Aqueous Media
  作者：Lidong Cao、Meihua Shen、Chaozhong Li

  DOI：10.1021/om050721c

  日期：2005.11.1

  Alkyl radical addition to (eta(6)-arene)tricarbonylmangenese complexes was investigated with SMI2, zinc, or indium as the radical initiator. Among them, the indium-mediated reactions of (eta(6)-arene)tricarbonylmangenese cations with various alkyl iodides in aqueous media afforded the corresponding radical addition-reduction products in moderate to excellent yields.
• Balssa, Frederic; Gagliardini, Vanessa; Rose-Munch, Francoise, Organometallics, 1996, vol. 15, p. 4373 - 4382
  作者：Balssa, Frederic、Gagliardini, Vanessa、Rose-Munch, Francoise、Rose, Eric

  DOI：——

  日期：——