| 239809-17-7

• CAS: 239809-17-7
• 化学式: C₃₂H₃₂B₂N₂O₆
• 分子量: 562.238
• InChiKey: LVKWZLRJEUAYTH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-羟基-N-(O-羟基苄亚基)乙基胺 、 3-甲氧基苯硼酸 以 苯 为溶剂， 以92%的产率得到
  参考文献：
  名称：

  New perspectives for boronic esters in macrocyclic chemistry

  摘要：

  In the present contribution a tetrameric macrocyclic compound derived from 2,6-pyridinedimethanol and 3-nitrophenyl boronic acid, as well as 10 new dimeric boronates prepared from 2-salicylideneaminoethanol and different aryl boronic acids such as a 2-methylphenyl-, 3-methylphenyl-, 4-methylphenyl-, 3-methoxyphenyl-, 4-methoxyphenyl-, 3-chlorophenyl-, 4-chlorophenyl-, 3-nitrophenyl-, 3-trifluoromethylphenyl- and 4-fluorophenylboronic acid are described. The tetrameric and three of the dimeric structures have been analyzed by X-ray crystallography, and a series of parameters such as bond length, bond angles, deviation of the boron atom from the boronate mean plane and intermolecular interactions are discussed. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(99)00054-6