[OsH2(η5-C6H4(CH2)2OMe)(triisopropylphosphine)2][Cl] | 801299-85-4

• 英文名称: [OsH2(η5-C6H4(CH2)2OMe)(triisopropylphosphine)2][Cl]
• CAS: 801299-85-4
• 化学式: C₂₆H₅₅OOsP₂*Cl
• 分子量: 671.323
• InChiKey: FRZBDUNHLUWXLV-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [OsH2(η5-C6H4(CH2)2OMe)(triisopropylphosphine)2][Cl] 在 KOH 作用下， 以 四氢呋喃 、 甲醇 为溶剂， 以92%的产率得到OsH(η5-C6H4(CH2)2OMe)(triisopropylphosphine)2
  参考文献：
  名称：

  Influence of the Solvent in the Synthesis of Osmium Complexes Containing Cyclopentadienyl Ligands with a Pendant Donor Group

  摘要：

  The course of the reactions between complex OsH2Cl2((PPr3)-Pr-i)(2) (1) and the functionalized cyclopentadienyllithium derivatives Li[C5H4(CH2)(2)E] (E = NMe2 (2), OMe (3)) strongly depenas on the solvent used. Thus, in the presence of donor solvents such as THF, the salts [OsH2{eta(5)-C5H4(CH2)(2)E}((PPr3)-Pr-i)(2)][OsHCl2(CO)((PPr3)-Pr-i)(2)] (E = NMe2 [4][5], OMe [6][5]) with a carbonylated osmium anion are produced, while in hydrocarbon solvents the chloride salts [OsH2{eta(5)-C5H4(CH2)(2)E}(PPr3)(2)]Cl (E NMe2 [4]Cl, OMe [6]Cl) are formed.

  DOI：

  10.1021/om049514n
• 作为产物：
  描述：

  bis(triisopropylphosphane)(dihydrido)dichloroosmium(IV) 、 Li((2-methoxyethyl)cyclopentadienyl) 以 甲苯 为溶剂， 以85%的产率得到[OsH2(η5-C6H4(CH2)2OMe)(triisopropylphosphine)2][Cl]
  参考文献：
  名称：

  Influence of the Solvent in the Synthesis of Osmium Complexes Containing Cyclopentadienyl Ligands with a Pendant Donor Group

  摘要：

  The course of the reactions between complex OsH2Cl2((PPr3)-Pr-i)(2) (1) and the functionalized cyclopentadienyllithium derivatives Li[C5H4(CH2)(2)E] (E = NMe2 (2), OMe (3)) strongly depenas on the solvent used. Thus, in the presence of donor solvents such as THF, the salts [OsH2{eta(5)-C5H4(CH2)(2)E}((PPr3)-Pr-i)(2)][OsHCl2(CO)((PPr3)-Pr-i)(2)] (E = NMe2 [4][5], OMe [6][5]) with a carbonylated osmium anion are produced, while in hydrocarbon solvents the chloride salts [OsH2{eta(5)-C5H4(CH2)(2)E}(PPr3)(2)]Cl (E NMe2 [4]Cl, OMe [6]Cl) are formed.

  DOI：

  10.1021/om049514n