[2-(hydroxymethyl)phenyl]iodo[1,1'-bis(diphenylphosphino)ferrocene]palladium | 353798-14-8

• 英文名称: [2-(hydroxymethyl)phenyl]iodo[1,1'-bis(diphenylphosphino)ferrocene]palladium
• CAS: 353798-14-8
• 化学式: C₄₁H₃₅FeIOP₂Pd
• 分子量: 894.847
• InChiKey: AEUGVQVSXAUSBE-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1,1'-双(二苯基膦)二茂铁 、 trans-[PdI{C6H4(CH2OH)-2}(PPh3)2] 以 二氯甲烷 为溶剂， 以98%的产率得到[2-(hydroxymethyl)phenyl]iodo[1,1'-bis(diphenylphosphino)ferrocene]palladium
  参考文献：
  名称：

  Synthesis and Structure of New Oxapalladacycles with a Pd−O Bond

  摘要：

  Reaction of the arylpalladium complex [Pd(2-C6H4CH2OSi-t-BuMe2)(PPh3)(2)I] (9) with n-Bu4NF gave the oxapalladacycle dimer [Pd(2-C6H4CH2O)I(PPh3)](2) (7). Similarly, [Pd(2-C6H4CH2O)I(AsPh3)](2) (11) was obtained by reaction of the arylpalladium complex [Pd(2C(6)H(4)CH(2)OSi-t-BuMe2)(AsPh3)(2)I] (10) with n-Bu4NF. The structure of dimer 7 was confirmed by single-crystal X-ray diffraction. Reaction of 7 or 11 with the bidentate ligands 1,1 ' -bis(diphenylphosphino)ferrocene and 1,10-phenanthroline gave the monomeric oxapalladacycle complexes 16 and 17. Complex 7 inserts tert-butyl isocyanide to form 1,1-dimethyl-N-1(3H)-isobenzofuranylidenethanamine (18). Reaction of [Pd(2-C6H4R)(PPh3)(2)X] (R = CHO, X = Br, 21; R = CO2H, X = Br, 24a; R = CO2H, X = I, 24b) with Ag2CO3 or Cs2CO3/AgBF4 afforded the tetrameric complex [Pd(2-C6H4CO2)(PPh3)](4) (22), whose structure was confirmed by X-ray diffraction.

  DOI：

  10.1021/om0010565