| 296280-39-2

• CAS: 296280-39-2
• 化学式: C₄₃H₅₂Br₂O₂Zr
• 分子量: 851.917
• InChiKey: AWNAAUSBERRYKR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  在 二氧化硫 作用下， 以 四氢呋喃 为溶剂， 生成 {(η5-C5H5)2ZrO}x
  参考文献：
  名称：

  General, Efficient Route to Thiophene-1-Oxides and Well-Defined, Mixed Thiophene-Thiophene-1-Oxide Oligomers

  摘要：

  DOI：

  10.1021/ja992365t
• 作为产物：
  描述：

  4,4-bis(hexyloxymethyl)-1,7-bis-p-bromophenyl-1,6-heptadiyne 、 (π-C5H5)2Zr 以 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  General, Efficient Route to Thiophene-1-Oxides and Well-Defined, Mixed Thiophene-Thiophene-1-Oxide Oligomers

  摘要：

  DOI：

  10.1021/ja992365t

文献信息

• Poly(2,5-diphenylgermole):  Incorporation of a Germole Ring into a Conjugated Polymer
  作者：Brett L. Lucht、Mihai A. Buretea、T. Don Tilley

  DOI：10.1021/om000191e

  日期：2000.9.1

  The intramolecular zirconocene coupling of 4,4-bis(hexyloxymethyl)-1,7-bis-p-halophenyl-1,6-heptadiynes provides 2,5-bis-p-halophenylzirconocyclopentadienes (bromo and chloro derivatives), which undergo efficient transmetalation reactions with GeBr(4). Methylation of the resulting dihalogermoles with MeLi provided bis-p-halophenyl-2,5-germole monomers. These functionalized germoles were polymerized via nickel coupling to give oligo- and poly(2,5-diphenylgermole) materials (7). Investigations of optical properties reveal that the monomers and a model 2,5-bisphenylgermole are somewhat photoluminescent (Phi = 0.018-0.12), while the high molecular weight polymer (M(n) approximate to 20 000) exhibits very efficient photoemission (Phi = 0.79). Electrochemical studies indicate that delocalization in 7 is accompanied by a modest lowering of the LUMO level relative to that of the monomer.