| 1351616-38-0

• CAS: 1351616-38-0
• 化学式: C₂₁H₁₅Cl₃FeI₄N₃
• 分子量: 979.194
• InChiKey: QLRQCXWTMXCGMR-YDAFMUNPSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  N-(3,5-diiodophenyl)-1-[6-[N-(3,5-diiodophenyl)-C-methylcarbonimidoyl]pyridin-2-yl]ethanimine 、 三氯化铁 以 正丁醇 为溶剂， 以65%的产率得到
  参考文献：
  名称：

  Iron(III) complexes with meta-substituted bis(arylimino)pyridine ligands: Catalyst precursors for the selective oligomerization of ethylene

  摘要：

  Bis(arylimino)pyridine iron(III) complexes containing meta-halogen substituents at the iminophenyl rings were synthesized and characterized. In contrast to iron(II) complexes, the presence of at least one ortho-substituent at the iminophenyl rings is not obligative for catalytic activities of these iron(III) complexes. After activation with methylaluminoxane (MAO), these catalysts oligomerize ethylene to give also internal and branched olefins besides the expected linear alpha-olefins. The widths of the resulting molecular weight distributions and the degrees of isomerization of the resulting oligomers strongly depend on the substitution pattern at the ligand frameworks. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2011.10.011