[BH3*(α,α'-bis(diphenylphosphino)-p-xylene)*Ru(p-cymene)Cl2] | 252032-17-0

• 英文名称: [BH3*(α,α'-bis(diphenylphosphino)-p-xylene)*Ru(p-cymene)Cl2]
• CAS: 252032-17-0
• 化学式: C₄₂H₄₅BCl₂P₂Ru
• 分子量: 794.554
• InChiKey: SPCZIANMOCKLTF-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  硼烷四氢呋喃络合物 、 [(α,α'-bis(diphenylphosphino)-p-xylene)*Ru(p-cymene)Cl2] 以 二氯甲烷 为溶剂， 以75.3%的产率得到[BH3*(α,α'-bis(diphenylphosphino)-p-xylene)*Ru(p-cymene)Cl2]
  参考文献：
  名称：

  [BH₃·PPh₂CH₂C₆H₄CH₂PPh₂·Ru(p-cym)Cl₂]:  A New Bifunctional Compound and Prototype of a Linked Borane/Metal Cluster Species

  摘要：

  The species [BH3. PPh2CH2C6H4CH2Ph2P .(p-cym)RuCl2], which is a bidentate phosphine ligand with a complexed Ru moiety at one end and a borane(1) group at the other end, has been prepared and characterized spectroscopically and the crystal structure reported. The molecule adopts a conformation in which the P atoms are syn to each other and the species exhibits novel long range 31P-31P NMR coupling.

  DOI：

  10.1021/ic990687s