[Fe₂(CO)₅PPh₃(μ-Te)₂] | 1430747-15-1

• 英文名称: [Fe₂(CO)₅PPh₃(μ-Te)₂]
• CAS: 1430747-15-1
• 化学式: C₂₃H₁₅Fe₂O₅PTe₂
• 分子量: 769.237
• InChiKey: PPPSMPZBVPAIEJ-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  Ru(phenylacetylene)(PPh3)2Cp 、 Fe3(μ3-Te)2(CO)9 以 四氢呋喃 为溶剂， 反应 0.5h， 以8%的产率得到[{μ-SeC(CpRu(PPh₃)(CO))=C(Ph)Se}(CO)₆Fe₂]
  参考文献：
  名称：

  Reaction of ruthenium phenyl acetylide with iron-chalcogen clusters and iron pentacarbonyl

  摘要：

  Photolysis of a THF solution containing ruthenium acetylide [(eta(5)-C5H5)Ru(PPh3)(2)(eta(1)-C CPh)] with [Fe-3(CO)(9)(mu(3)-Se)(2)] cluster affords an adduct [{mu-SeC(CpRu(PPh3)(CO))=C(Ph)Se)(CO)(6)Fe-2] (1), while under similar reaction condition with [Fe-3(CO)(9)(mu(3)-Te)(2)] cluster a Ru-inserted product [(eta(5)-C5H5)(PPh3)(eta(1)-C CPh)RuFe2(mu(3)-Te)(2)(CO)(6)] (2) was obtained. Under thermal condition [(eta(5)-C5H5)Ru(PPh3)(2)(eta(1)-C CPh)] react with Fe(CO)(5) to give an acetylide stabilised Fe2Ru mixed metal cluster [(eta(5)-C5H5)RuFe2(CO)(7)(eta(2):eta(2):eta(1)-C=CPh)], (3). (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2013.02.001