Salen((t)Bu)AlCCPh | 681829-60-7

• 英文名称: Salen((t)Bu)AlCCPh
• CAS: 681829-60-7
• 化学式: C₄₀H₅₁AlN₂O₂
• 分子量: 618.839
• InChiKey: ZMYVWPXEOVPJQG-GIPDMEFXSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  Salen((t)Bu)AlCl 、 lithium phenylacetylide 以 四氢呋喃 为溶剂， 以84%的产率得到Salen((t)Bu)AlCCPh
  参考文献：
  名称：

  Five-coordinate organoaluminum acetylides and crystal structure of the hydrosylate, [Salophen(tBu)Al]2O

  摘要：

  The first examples of five coordinate aluminum acetylide compounds chelated by a single ligand are reported in this paper. The combination of L('Bu)AlCl (where L = Salen (1), Salpen (2), Salophen (3), Salomphen (4)) with LiCdropCPh in THF at -78degrees C leads to the formation of the four acetylides (5-8), LCdropCPh. These are extremely moisture sensitive and readily hydrolyze to form aluminum hydroxides and with condensation form compounds of formula [L('Bu)Al](2)O. The hydrosylate [Salophen('Bu)Al](2)O (9) has been structurally characterized. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2003.12.011