[Pd(η3-C3H5)(C(PPh2)(P(S)Ph2)2)] | 1031444-16-2

• 英文名称: [Pd(η3-C3H5)(C(PPh2)(P(S)Ph2)2)]
• CAS: 1031444-16-2
• 化学式: C₄₀H₃₅P₃PdS₂
• 分子量: 779.191
• InChiKey: XROGTCBQOHWFER-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  [Pd(η3-C3H5)(HC(PPh2)(P(S)Ph2)2)]SbF6*0.5CH2Cl2 在 triethyl amine 作用下， 以 四氢呋喃 为溶剂， 生成 [Pd(η3-C3H5)(C(PPh2)(P(S)Ph2)2)]
  参考文献：
  名称：

  Hemilability and nonrigidity in metal complexes of bidentate P,PS donor ligands

  摘要：

  Hemilability and nonrigidity in a series of mixed P, P=S donor ligands has been studied in the complexes [Pd(P, P=S)Cl(2)], [Pd(eta(3)-C(3)H(5)) (P, P=S)][SbF(6)], and [Rh(cod)(P, P=S)][SbF(6)] (P, P=S = Ph(2)P-Q-P(S)Ph(2)). The effect of bite angle, the rigidity of the ligand backbone, and the role of the ancillary ligands are discussed. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.10.044