dichloro[κ-P-η6-(R)-tert-butyl(2-(2,3,4,5,6-pentamethylphenyl)ethyl)phosphine]ruthenium(II) | 1021183-48-1

• 英文名称: dichloro[κ-P-η6-(R)-tert-butyl(2-(2,3,4,5,6-pentamethylphenyl)ethyl)phosphine]ruthenium(II)
• 英文别名: [RuCl₂(κ-P(t-Bu)MeCH₂CH₂-η⁶-C₆Me₅)]；dichloro(κP-η6-(R)-tert-butyl(2-(2,3,4,5,6-pentamethylphenyl)ethyl)methylphosphine)ruthenium(II)
• CAS: 1021183-48-1
• 化学式: C₁₈H₃₁Cl₂PRu
• 分子量: 450.394
• InChiKey: NZNVLKWVAVATOP-VLEZWVESSA-L

反应信息

• 作为产物：
  描述：

  [RuCl₂(η⁶-p-cymene)(P(t-Bu)MeCH₂CH₂C₆Me₅)] 以 氯苯 为溶剂， 生成 dichloro[κ-P-η6-(R)-tert-butyl(2-(2,3,4,5,6-pentamethylphenyl)ethyl)phosphine]ruthenium(II)
  参考文献：
  名称：

  Synthesis and Reactivity of P-Chiral Tethered (η¹:η⁶-phosphinoarene)ruthenium Complexes

  摘要：

  A new group of tethered phosphinoarene ruthenium complexes containing a stereogenic center at the phosphine atom is presented. The introduction of other elements of chirality, either as a plane or at the ruthenium center, is explored.

  DOI：

  10.1021/om800076x